Bamboo,
one of the most abundant biomaterials, has been used as
a building material since ancient times; however, its application
in functional materials has been rarely explored. Herein, a highly
robust and conductive carbonized bamboo aerogel (CBA) is obtained
from the natural bamboo through a simple three-step process of pulp
oxidization, freeze-drying, and carbonization. The CBA obtained shows
not only a low density of 0.02 g/cm3 but also a high conductivity
of 6.42 S/m and remarkable elasticity with a maximum recoverable compressive
strain of 60% due to its unique three-dimensional (3D) network randomly
stacked with the hybrid structure of carbonized bamboo fibers and
films. After encapsulation with silicone resin, the CBA/silicone composite
prepared exhibits excellent flexibility and stretchability with a
low Young’s modulus (0.09 MPa) and a large failure strain (275%).
Importantly, the CBA/silicone composite also offers remarkable strain-sensing
performance with a maximum gauge factor of 30.6, a short responsive
time of 50 ms, and a stable response to cyclic loading over 1000 cycles,
which is comparable to those of the piezoresistive composites based
on expensive nanomaterials. Moreover, the CBA/silicone composite demonstrates
the capability as a wearable strain sensor for human motion recognition
comprising finger bending, breathing, and throat movement. Considering
the green and sustainable nature of bamboo as a raw material, combined
with the excellent piezoresistive performance, low production cost,
and simple preparation process, the flexible strain sensors with CBA/silicone
composite as a sensing element are promising in wearable electronic
devices, personalized healthcare, and artificial intelligence systems.