2005
DOI: 10.1021/ie0487843
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Abstract: Oligomerization of hexene and heavier olefins is important for synthetic fuel producers to reduce refinery complexity, as well as to produce good quality middle distillates and lubricating oils. Conversion of such olefins with homogeneous catalysts is much easier than with solid acid catalysts, which are prone to deactivation and are limited to middle distillate production. Solid phosphoric acid, amorphous silica-alumina, sulfated zirconia, MCM-41, ZSM-5, zeolite-Y, and zeolite-omega heterogeneous catalysts we… Show more

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Cited by 85 publications
(88 citation statements)
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“…These reaction products were also found by de Klerk [11] over solid phosphoric acid and Grigor'eva [12] over a zeolite Y. [10] suggested that double bond isomerization is the main reaction at low temperatures and cracking and hydrogen transfer products become important at temperatures higher than 473K for 1-octene oligomerization. Also, he announced that C 8 isomers are susceptible to cracking themselves, so this reaction and the oligomerization proceed in parallel.…”
Section: Reaction Networksupporting
confidence: 57%
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“…These reaction products were also found by de Klerk [11] over solid phosphoric acid and Grigor'eva [12] over a zeolite Y. [10] suggested that double bond isomerization is the main reaction at low temperatures and cracking and hydrogen transfer products become important at temperatures higher than 473K for 1-octene oligomerization. Also, he announced that C 8 isomers are susceptible to cracking themselves, so this reaction and the oligomerization proceed in parallel.…”
Section: Reaction Networksupporting
confidence: 57%
“…As for 1-octene oligomerization only a few works are available in the open literature. De Klerk [10] evaluated the liquid-phase oligomerization of 1-octene in the temperature range 373-573K over some solid acid catalysts, such as solid phosphoric acid, amorphous silica, sulfated zirconia, MCM-41 and some zeolites. He found that between 373K and 473K the main products were C 16 dimers but deactivation occurred rapid.…”
Section: Introductionmentioning
confidence: 99%
“…Another advantage is that the oligomerization is flexible in terms of the average molecular weight of the hydrocarbon product and thus in terms of the composition (gasoline, JET, and gas oil fractions). The oligomerization has already been studied by using a variety of catalysts [3], such as solid phosphoric acid [4][5][6], zeolites [7][8][9][10][11][12][13][14][15], acidic ion exchange resins [14][15][16][17][18][19][20], metal oxide catalysts [21][22] and ionic liquids [23][24][25][26].…”
Section: Introductionmentioning
confidence: 99%
“…With increasing the size of the modifying cations the dimer selectivity increased. Yoon [9][10][11][12][13][14], primarily isobutene trimerization on different zeolite catalysts (e.g. beta zeolite, USY zeolite, mordenite, ferrierite).…”
Section: Introductionmentioning
confidence: 99%
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