Nonlinear effect of two remembered guests in their mixtures on the host memory for guest inclusion and release

Gabdulkhaev, Mukhammet N.; Gatiatulin, Askar K.; Зиганшин, Марат А.; Gorbatchuk, Valery V.

doi:10.1007/s10973-016-5558-8

Cited by 5 publications

(4 citation statements)

References 18 publications

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“…This selectivity of tertbutylcalix[6]arene may be used in the analysis of binary mixtures if at least one of their components is from the first group. The efficiency of this analysis was demonstrated using DSC for the binary mixtures with one (Safina et al, 2013) and two (Gabdulkhaev et al, 2016) remembered components.…”

Section: Smart Molecular Recognition: Selectivity By Host Memory For mentioning

confidence: 99%

“…Guest-induced metastable polymorphs of calixarenes capable of an exothermic solid-phase transition have also a potential in 100% separation of binary mixtures of close homologs (Morohashi et al, 2017;Morohashi and Hattori, 2018) or compounds with close boiling points (Gabdulkhaev et al, 2016).…”

Section: Smart Molecular Recognition: Selectivity By Host Memory For mentioning

confidence: 99%

See 1 more Smart Citation

Smart Molecular Recognition: From Key-to-Lock Principle to Memory-Based Selectivity

2020

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The formation and decomposition of inclusion compounds with a solid-solid phase transition may be very selective to the guest molecular structure. This selectivity may function in essentially different ways than defined by the classical concept of molecular recognition, which implies the preferential binding of complementary molecules. Solid inclusion compounds may take part as an initial or/and final state in several processes of different types summarized in this review, which selectivity is boosted by cooperativity of participating molecular crystals. Some of these processes resemble switching electronic devices and can be called smart giving practically absolute molecular recognition.

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Section: Smart Molecular Recognition: Selectivity By Host Memory For mentioning

confidence: 99%

Section: Smart Molecular Recognition: Selectivity By Host Memory For mentioning

confidence: 99%

Smart Molecular Recognition: From Key-to-Lock Principle to Memory-Based Selectivity

2020

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“…18 Inspired by the intriguing synthetic methods and rich host-guest properties, a set of novel supramolecular macrocycles such as calixarenes, hybridarenes, biphenarenes, tiaraarenes and lean pillararenes have been reported. [19][20][21][22][23][24][25] In recent years, Huang and coworkers have reported a kind of adsorptive separating materials named nonporous adaptive crystals (NACs), which employ activated crystals of supramolecular macrocycles to adsorb specific guests. 26 These crystalline materials can endure harsh environments like moist and thermal conditions.…”

Section: Introductionmentioning

confidence: 99%

Selective separation of 2,5-dimethylfuran and 2,5-dimethyltetrahydrofuran using nonporous adaptive crystals of a hybrid[3]arene

Liu,

2023

New J. Chem.

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“…Characterization of calixarenes/calixresorcinarenes layers to be applied as sensors is carried out by several methods such as thermal analysis [39][40][41][42][43][44][45][46][47].…”

Section: Introductionmentioning

confidence: 99%

Calix[4]resorcinarene macrocycles

Eddaif

Trif

Telegdi

et al. 2019

J Therm Anal Calorim

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Supramolecular chemistry is an interdisciplinary scientific field, including chemical, physical and biological properties of more complex chemical species than the molecules themselves. Calixarenes/calixresorcinarenes are macrocyclic compounds, consisting of 'n' phenolic/resorcinolic units linked together by methylene bridges; these macrocycles are often used for molecular recognition. Thus, different modifications can be made to both the lower and upper rim, allowing the construction of well-defined multivalent buildings. In this work, three calix[4]resorcinarene macrocycles were synthesized, namely C-dec-9-en-1-ylcalix[4]resorcinarene (CAL 11U), C-trans-2, cis-6-octa-1,5-dien-1-ylcalix[4]resorcinarene (CAL 9U) and C-nonylcalix[4]resorcinarene (CAL 10) by a simple condensation reaction. The compounds CAL 11U and CAL 10 have been already synthesized by researchers, while the CAL 9U has been synthesized for the first time. Their structures were confirmed using ATR-FTIR, 1 H NMR and 13 C NMR. Thermal analysis combined with mass spectrometric evolved analysis of the vapors was used to study the thermal behavior of the different synthesized molecules, and they were the subject of characterization by X-ray powder diffraction in order to analyze their degree of crystallinity.

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Nonlinear effect of two remembered guests in their mixtures on the host memory for guest inclusion and release

Cited by 5 publications

References 18 publications

Smart Molecular Recognition: From Key-to-Lock Principle to Memory-Based Selectivity

Smart Molecular Recognition: From Key-to-Lock Principle to Memory-Based Selectivity

Selective separation of 2,5-dimethylfuran and 2,5-dimethyltetrahydrofuran using nonporous adaptive crystals of a hybrid[3]arene

Calix[4]resorcinarene macrocycles

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