volume 350, issue 11-12, P1855-1866 2008
DOI: 10.1002/adsc.200800201
View full text
|
|
Share

Abstract: Abstract: On activation by MAO the (imino)pyridine cobalt(II) complex CoCl 2 N 2 Ph/i-Pr 2 catalyzes the enchainment of one norbornene (NB) molecule with two ethylene molecules to give exo-2,exo-3-ethylvinylnorbornane with high activity and complete diastereoselectivity. Turnover frequencies [TOF, mol NB (mol Co h) À1] as high as 270,000 have been obtained. The 2E-1NB hetero-trimerization reaction has been also accomplished with NBs bearing polar substituents such as norbornenemethanol and norbornenecarboxyli…

Expand abstract

Search citation statements

Order By: Relevance

Paper Sections

0
0
0
0
0

Citation Types

0
9
0

Publication Types

Select...

Relationship

0
0

Authors

Journals