volume 108, issue 1, P187-194 1981
DOI: 10.1002/pssb.2221080122
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Abstract: The absorption spectra of KIz, CdI,:Ni2+, and CoI, in the wave-number region 4000 to 16000 cm-l are reported. The spectra are interpreted in terms of d-d transitions of NiZ+ and Co2+ ions. Parameters of the electron repulsion, cubic crystal field, and spin-orbit coupling are estimated. From the latter the transferred spin densities are deduced and compared with Mossbauer data. Birefringence experiments as a function of the temperature show the presence of two phase transitions in XI,.Nous avons mesure les spe…

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