proportion of the added ammonium that was adsorbed onto the exchange sites was linear up to 200 pg N 5l application, but the amount fixed by the clays was linear to onl)'about 100 pg N g-l application rate-Data from studies where soil columns were leached with NH4NO, piovided only limited information'on the relaiive importance of exchange versus fixation processes to the adsorption of amironium. Leachingcolumns with a limited number of batches of NH4NO, fo.llowed by water (short cycle) were usefui for comparing the ability of"different soils to adsorb and retain ammonium, bui thd relative.importance of exchanle versus frxation could not be determined. In the I 8 samples of this study, the amount of NHo+ adsorbed ranged from 84 to 25o/o dxr.-ing short cycle column leachings. Different pattemi of adsorption occuned among the four soil samples that were leached with a iarge number of batches of ai-rmonium (long cycle), but it iould not be determined whether or not these pattgrns were related to diiferences in proportions of fixation relative to exchange. Measurements showed that ammonium was fixed in the soils during the long cycli leichings but that the amounts of fixed ammonium measured were influenced by air drying the sample before anilysis. Slveral studies riith and without toluene additions showed that microbial activity must be controlled during these measurements. It was concluded that south coastal soils contained significant amounts of fixed ammonium and can fix additional ammonium. The amount of ammonium in the clay fixed pool and the potential to fix added ammonium was different in relation to the soil type, their previous management, and wetting and drying cycles. The biological significance of fixed ammonium and the fixation process must not be discounted in any nitrogen studies of these soils for proper interpretation of data.