SUMMARYAn experimental investigation of the degradation of styrene acrylonitrile (SAN) exposed to corona discharge under ambient conditions was presented. SAN specimens were subjected to a corona stress generated by two plane parallel electrodes. The surface physicochemical changes were studied using scanning electron microscope, energy-dispersive X-ray analysis, Fourier transformed infrared spectroscopy and surface resistance measurements.The results showed significant damage on the specimen' surface caused by the corona discharge. Surface erosion was seen in the micrographs and colour change was observed on the aged surface.The surface resistance dropped rapidly during the first hours of exposure to the corona discharge, then approached a saturation value asymptotically. It was established that hydrophilic hydroxyl (O-H) and carbonyl (C --O) groups have formed on the surface of the aged sample. Moisture adsorbed by the hydrophilic OH groups plays an important role in the decrease of the surface resistance, as, under dry conditions after removal from the corona discharge, the surface resistance increased and tended to recover its original value.