2011
DOI: 10.1039/c0cs00188k
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Abstract: The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging research topic in the field of molecular magnetism. An essential driving force for the interest in this area is the fact that heavier metal ions introduce important attributes to the physical properties of paramagnetic compounds. Among the attractive characteristics of heavier elements vis-à-vis magnetism are the diffuse nature of their d orbitals, their strong magnetic anisotropy owing to enhanced spin-orbit coupling, and … Show more

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Cited by 381 publications
(265 citation statements)
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“…The use of heavier transition metal complexes in the design of low-dimensional nanomagnets has a better hand. First of all they possess more diffuse valence orbitals than 3d metals that can provide stronger magnetic exchange interactions [32]. Further, the ions of these metals can be in different oxidation states having a small difference in the ox-red potentials that is favorable to generate charge transfer reactions by electrical or light irradiation.…”
Section: Introductionmentioning
confidence: 99%
See 1 more Smart Citation
“…The use of heavier transition metal complexes in the design of low-dimensional nanomagnets has a better hand. First of all they possess more diffuse valence orbitals than 3d metals that can provide stronger magnetic exchange interactions [32]. Further, the ions of these metals can be in different oxidation states having a small difference in the ox-red potentials that is favorable to generate charge transfer reactions by electrical or light irradiation.…”
Section: Introductionmentioning
confidence: 99%
“…Cyano-bridged metal assemblies have provided a large number of compounds with SMM [31][32][33][34][35][36][37][38] and SCM behavior [39][40][41][42][43][44][45][46][47][48]. The greater part of these materials comprises 3d metal ions as the core magnetic units.…”
Section: Introductionmentioning
confidence: 99%
“…For this purpose, structure-property relationships are investigated systematically and strategies for a rational construction of their crystal structures are required. Compounds that consist of paramagnetic metal cations are of particular interest because they can show different magnetic properties and thus it is not surprising that an increasing number of new compounds were recently reported [5][6][7][8][9][10][11][12][13][14]. One group of these compounds are transition metal thiocyanato coordination polymers, which show a variety of different coordination modes including the terminal and the bridging coordination, with the latter being of special importance because cooperative magnetic properties can be expected [15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32][33][34].…”
Section: Introductionmentioning
confidence: 99%
“…These transitions can be as simple as low ↔ high spin in an isolated molecule or as complex as antiferromagnetic ↔ ferromagnetic, metamagnetic, and quantum critical processes in extended solids [2][3][4][5][6][7][8][9][10][11][12] . Spin crossovers in 4 and 5d-containing compounds are particularly interesting because spin-orbit coupling competes with electron correlations to reveal exotic properties [13][14][15][16][17][18][19] .…”
Section: Introductionmentioning
confidence: 99%