MOFs for Ultrahigh Efficiency Pulsed Laser Micropropulsion

Abstract

Conventional propellant materials, such as polymers and single metal elements, have long been investigated for their potential in pulsed laser micropropulsion (LMP) technology. However, achieving superior LMP efficiency through physical mixing of these materials remains a significant challenge. In this study, we present a paradigm shift by introducing porous crystalline polymers, known as Metal‐Organic Frameworks (MOFs), as novel propellants in pulsed LMP. MOFs are composed of metal cations and organic ligands that form ordered structures through coordination, eliminating the problem of local hot zones arising from uneven physical mixing encountered in LMP. In direct comparison to conventional polymers and single element targets, MOFs exhibit substantially higher LMP efficiency. By precisely tailoring the metal atom fraction within MOFs, an extraordinary ultrahigh efficiency of 51.15% is achieved in pulsed LMP, surpassing the performance of similar materials previously reported in the literature. This pioneering application of MOFs not only revolutionizes the field of laser micropropulsion but also opens up new frontiers for MOF utilization in various energy applications.This article is protected by copyright. All rights reserved

A Review on Micro-Combustion Flame Dynamics and Micro-Propulsion Systems

“…Nevertheless, the widespread adoption of LMP technology is limited by the proper selection of propellant. Recently, Rao et al [146,147] presented an innovative LMP technology using metal-organic frameworks (MOFs) and also MOF-derived Carbon-encapsulated-Nano-Metal Composites (CNMC) as the propellant. The characteristic structure in CNMC overcomes the challenge of local hot zones caused by uneven physical mixing encountered in traditional LMP approaches.…”