volume 33, issue 8, P486-496 1993
DOI: 10.1002/pen.760330807
View full text

Abstract: Abstract The generalization of a multiordering parameter model to treat physical aging in polymeric glasses is more fully explored. In the past, this model has successfully rationalized most aspects of time dependent volume and enthalpy behavior; however, only qualitative agreement between predictions of the generalized model and experiment were previously achieved for physical aging. Now, by paying strict attention to the specific analytical form of the shift factor expression, quantitative predictions have …

expand abstract