In a recent paper (Hansen, 2020), we proposed an interpretation of some of the terms of the continuous-time random walk (CTRW) generalized master equation (GME), which allow its 1D form to be written in the following simplified way:(1)Here, c[ML −3 ] is concentration, M(t) [T −1 ] is a temporal memory function, ̄ LT −1 is mean groundwater velocity, and α [L] is a standard Fickian dispersivity, generated by multiplication of 𝐴𝐴 𝐴 𝐴𝐴 by some fixed, medium-specific dispersivity, α [L]; x [L] is spatial coordinate, and t [T] is time. On this approach, M(t) is defined in the Laplace domain according the formula:where superscript tilde denotes the Laplace transform, s [T −1 ] is the Laplace variable, and ψ(t) [T −1 ] is the probability distribution function for a subordination mapping representing the total time taken for solute to complete a transition that would have taken unit time under purely advective-dispersive physics as described by 𝐴𝐴 𝐴 𝐴𝐴 and α.This approach, which we refer to as the simplified approach, simplifies and physically constrains the continuous-time random walk (CTRW) generalized master equation (GME) in a number of ways and also provides an interpretation to its parameters. By contrast, in typical usage: (a) 𝐴𝐴 𝐴 𝐴𝐴 and
𝐴𝐴𝐴𝐴 𝐴 𝐴𝐴 are replaced with arbitrary fitting parameters v ψ and D ψ that do not generally have any specific relation to groundwater velocity, (b) the definition of M typically contains an arbitrary "time constant" fitting parameter with no specific interpretation, τ [T], in its numerator, and (c) the transition time distribution, ψ(t) has no particular definition; it is an additional fitting "parameter." For clarity, the standard continuous-time random walk (CTRW) generalized master equation (GME) and transformed memory function corresponding to Equations 1 and 2 are (Berkowitz et al., 2006):