2007
DOI: 10.1002/chin.200740048
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Catalina Ferrer, Mihai Raducan, Cristina Nevado et al.

Abstract: and Platinum(II)-Catalyzed Cyclization of 1,6-Enynes. -In the presence of Pt(II) catalysts, enynes of type (I)/(VII) undergo less common 6-endo-dig cyclization to fused pyran derivatives such as (II) and (VIII). Starting from simple enynes like (XV), skeletal rearrangement takes place which affords products of type (XVI), (XVII) and/or (XVIII). Using Au(I) catalysts, some enynes undergo unexpected rearrangement to oxepins, bicyclic or polycyclic ring systems. The cyclization of dienynes does not give desired …

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