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“…The coordinates Tc and c have a great importance in calculation the values of coefficient of thermal expansion,  and the variation of thermal expansion coefficient  below and above Tg of the materials under investigation using the following formula [42] The values of  and  are estimated and summarized in Table 4. These values are found to be in good agreement with the values of many polymers [2,16]. Values of both Tc and c can be used to interpret the basic characteristics of the polymer state when affected by both the bonding environment and polar groups.…”
Section: Ts-rmasupporting
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“…The coordinates Tc and c have a great importance in calculation the values of coefficient of thermal expansion,  and the variation of thermal expansion coefficient  below and above Tg of the materials under investigation using the following formula [42] The values of  and  are estimated and summarized in Table 4. These values are found to be in good agreement with the values of many polymers [2,16]. Values of both Tc and c can be used to interpret the basic characteristics of the polymer state when affected by both the bonding environment and polar groups.…”
Section: Ts-rmasupporting
“…Thermally stimulated depolarization currents technique is applied to investigate the electrical properties of polymeric materials and their changes when are exposed to treatments that lead to formative changes. TSDC method is highly sensitive to probe the motions of polar groups or space charges in polymers [2][3][4][5][6][7].…”
Section: Introductionmentioning
“…The samples PMMA and PVDF and their blends with different ratio of PMMA to PVDF were obtained by using a twin screw extruder with the temperatures maintained at 473 K [ 26 ]. The samples were compression-molded at a temperature of 473 K and 30 MPa pressure during 10 min to form the disk-like samples and subsequent cooling of the press form to room temperature in the air on a table top.…”
Section: Study Of the Thermally Stimulated Depolarization Current In ...mentioning
“…Another method is to use blends of miscible polymers, one crystallizing and the other not. Classical examples are polycarbonate (PC)/polymethylmethacrylate (PMMA) blends, , PMMA/poly­(vinylidene difluoride) blends, and PMMA/PEO blends. , This allows for tuning of not only the crystallinity but also the glass transition temperature of the sample. The chains of the noncrystallizing polymer are expelled from crystalline lamellae.…”
Section: Introductionmentioning