Microwave spectrum, boron skeletal structure, and dipole moment of 5-fluoro-2,4-dicarboheptaborane(7) (C2B5H6F)

Durso, S. S.; Sheeks, R.; O'Gorman, Eileen; Beaudet, Robert A.

doi:10.1021/ic00308a003

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Dicarbaboranes1

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1989

1992

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Cited by 13 publications

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“…Carborane 36 is the compound on which the first two-dimensional NMR study in the area of boroncluster compounds was performed.67® Durso et al 176 have recently used microwave techniques to determine the structure and dipole moment of 5-F-doso-2,4-C2B5H6 (for structure see 36). They found that the interboron distances are comparable with those obtained for the parent compound1,5 and the relatively short B-F distance (133.0 (3) pm) was interpreted in terms of partial double-bond character.…”

Section: Dicarbaboranesmentioning

confidence: 99%