Microwave-assisted regioselective reaction of furanone derivative supported by DFT stimulation and molecular docking to afford controlling insecticidal agents

Rizk, Sameh A.; Atta-Allah, Saad R.

doi:10.1007/s13738-021-02202-2

Cited by 6 publications

(4 citation statements)

References 60 publications

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“…The static contact angle 159.56° for crude oil and the dynamic contact angle 149.55° for completely oil-wet means the system has transformed from oil-wet to intermediate oil-wet. The surfactant NOMS adsorption on the rock surface causes the change in the wettability/contact angle at the interface due to the solvation between the alkyl group of surfactants and the hydrophobic group of the crude oil (Rizk and Atta-Allah 2021 ). Afterward, the surfactant spreads in the aqueous phase, increasing the hydrophilicity of the system producing displacement for the oil from the rock pores to remove it and changed to water-wet phase.…”

Section: Resultsmentioning

confidence: 99%

Microwave-ultrasonic assisted extraction of lignin to synthesize new nano micellar organometallic surfactants for refining oily wastewater

Alhalafi,

Rizk,

Al-Malki

et al. 2024

Bioresour. Bioprocess.

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In this work, a beneficial approach for efficient depolymerization of lignin and controllable product distribution is provided. Lignin, an abundant aromatic biopolymer, has the potential to produce various biofuels and chemical adsorption agents and is expected to benefit the future circular economy. Microwave-ultrasonic (MW/US) assisted efficient depolymerization of lignin affords some aromatic materials used in manufacturing the starting material to be investigated. Some nano organometallic surfactants (NOMS) based on Ni2+, Cu2+, Co2+, Fe3+, and Mn2+ besides 2-hydroxynaphth-sulphanilamide are synthesized to enhance oil recovery (EOR). In this work, the assessment of the NOMS’s efficiency was improving the heavy oil recovery via the study of the dynamic interfacial tension (IFT), contact angle, and chemical flooding scenarios. The NOMS-Ni2+ exhibited the maximum reduction of viscosity and yield values. Dropping the viscosity to 819.9, 659.89, and 499.9 Pa s from blank crude oil viscosity of 9978.8, 8005.6, and 5008.6 Pa s respectively at temperatures of 40, 60, and 80 °C was investigated. The reduction of τB values was obtained also by OMS-Ni2+. The minimum IFT was recorded against the Ni2+ derivatives (0.1 × 10–1 mN m−1). The complete wettability alteration was achieved with the NOMS-Ni2+ surfactant (ɵ $$\cong 6.01).$$ ≅ 6.01 ) . The flooding test has been steered in 3 sets using the sand-packed model as a porous media at surfactant concentrations (1, 1.5, 2 and 2.5%) at 50 °C and 499 psi as injection pressure. The best value (ORs) formed for NOMS-Ni2+ were 62, 81, 85.2, and 89% respectively as compared with other NOMS-M2+ at the same concentrations. The mechanism of alternating wettability was described in the text. The rheology of the used heavy crude oil was investigated under temperatures of 40, 60, and 80 °C. Graphical Abstract

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Section: Resultsmentioning

confidence: 99%

Microwave-ultrasonic assisted extraction of lignin to synthesize new nano micellar organometallic surfactants for refining oily wastewater

Alhalafi,

Rizk,

Al-Malki

et al. 2024

Bioresour. Bioprocess.

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“…129,130 The usage of pyrazoles as antioxidants in fuels, anesthetics, and agricultural uses, as well as in pharmaceuticals and dyes, 131 has attracted attention from researchers. [132][133][134] These substances are helpful for materials chemistry, brightening, and electroluminescence. 135 They can also be utilized as organic light-emitting diodes, 136 Scheme 34 Sulfonation reactions of 2'-hydroxychalcone.…”

Section: Organic and Biomolecular Chemistry Reviewmentioning

confidence: 99%

Synthesis, reactions and application of chalcones: a systematic review

2023

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“…The antimicrobial action was also dose-dependent, therefore the MIC of produced Spiro compounds (1)(2)(3)(4)(5)(6)(7)(8)(9)(10)(11)(12)(13)(14)(15)(16) for each Pathogenic organism was measured. Various concentrations of (25,50,100,200,400 g/ml) were tested to reach this goal.…”

Section: Biological Activitymentioning

confidence: 99%

“…Quinazolinones and quinazolines are noteworthy in medicinal chemistry [1,2], quinazolinone nucleus stability pushed a lot of researchers to introduce many bioactive moieties to this nucleus to produce new potential medicinal agents [3]. From a literature survey, the quinazolin-4 (3H)-one derivatives are of interest because of their wide biological activities [4][5][6][7][8][9][10][11][12][13] carrying antimicrobial sites as considered a wide array of pharmaceutical properties [14][15][16][17][18][19][20][21][22][23]. Moreover, quinazolinones are considered the most important component of most natural alkaloids in some families of plants, animal, and microorganisms [24].…”

Section: Introductionmentioning

confidence: 99%

Microwave‐ultrasonic assisted synthesis, and characterization of novel 3′‐(amino, hydrazino and hydrazide)‐6′‐bromo‐spiro(isobenzofuran‐1,2′‐quinazoline)‐3,4′‐dione derivatives as antimicrobial agents

Algohary

Hassan

Rizk

2023

Journal of Heterocyclic Chem

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By attempts to construct new antimicrobial agents, a series of mono-and dibromo of 3 0 -(oxiranyl, hydrazide, oxadiazolo and pyrazolo)-methylene-spiro [isobenzofuran-1,2 0 -quinazoline]-3,4 0 (3 0 H)-dione derivatives were synthesized through the interaction between 6-bromo and/or 6,8-dibromo-spiroiso-benzofuran-1,2 0 -quinazolindione with carbon electrophiles, namely, ethyl chloroacetate, epichlorohydrin, chloroacetyl chloride and phosphorus pentasulfide (P 2 S 5 ). Reaction of ethylester of spiroquinazolindione with hydrazine hydrate under MW-US and UV reaction condition (green tool saves time and energy) to afford spiroquinazolindione hydrazide that used as preparatory materials for the synthesis of novel spiroquinazolin-dione. Most of the created compounds were evaluated in vitro for their antibacterial and antifungal activity.The 6-bromo or 6,8-dibromo quinazolin-3,4-dione nucleus bears oxirane hydrazino acetyl, hydrazide, oxadiazole and pyrazole moieties at position (3) and were the most potent against the gram-positive bacteria, gram-negative bacteria, and fungi comparable to Chloramphenicol and Fluconazole.

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Microwave-assisted regioselective reaction of furanone derivative supported by DFT stimulation and molecular docking to afford controlling insecticidal agents

Cited by 6 publications

References 60 publications

Microwave-ultrasonic assisted extraction of lignin to synthesize new nano micellar organometallic surfactants for refining oily wastewater

Microwave-ultrasonic assisted extraction of lignin to synthesize new nano micellar organometallic surfactants for refining oily wastewater

Synthesis, reactions and application of chalcones: a systematic review

Microwave‐ultrasonic assisted synthesis, and characterization of novel 3′‐(amino, hydrazino and hydrazide)‐6′‐bromo‐spiro(isobenzofuran‐1,2′‐quinazoline)‐3,4′‐dione derivatives as antimicrobial agents

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