Micro-nano Na3V2(PO4)3/C derived from metal-organic frameworks for high performance sodium ion batteries

Chen, Hongxia; Yang, Yutian; Nie, Rihuang; Li, Cheng; Xu, Shuangwu; Zhou, Mengcheng; Zhang, Xinyu; Zhou, Hongming

doi:10.1016/j.jallcom.2022.167695

Cited by 12 publications

(10 citation statements)

References 37 publications

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“…Recently, amorphous carbon‐coated hierarchical porous micro‐nano Na 3 V 2 (PO 4 ) 3 (NVP/C) materials with high specific surface area and highly conductive network between surface and particles were synthesized for cathodic applications in SIBs, as portrayed in Figure 16b. [ 374 ] The M‐NVP/C cathode material exhibited remarkable electrochemical properties, such as outstanding rate capability of 95.0 mAh g −1 at a current density of 10 C and extraordinary stable cycle life with the capacity decays from 111.2 mAh g −1 to 108.8 mAh g −1 after 500 cycles at 1 C, with a capacity retention rate of 97.8%. This MOF‐derived strategy is also viable in the modification of other unusual phosphates apart from NVP.…”

Section: Mof Derivatives As Sib Electrodesmentioning

confidence: 99%

Section: Mof Derivatives As Sib Electrodesmentioning

confidence: 99%

mentioning

confidence: 99%

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Metal–Organic Framework‐Based Materials for Advanced Sodium Storage: Development and Anticipation

Zhou,

Reddy,

Zhong

et al. 2024

Advanced Materials

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As a pioneering battery technology, even though sodium‐ion batteries (SIBs) are safe, non‐flammable, and capable of exhibiting better temperature endurance performance than lithium‐ion batteries (LIBs), because of lower energy density and larger ionic size, they are not amicable for large‐scale applications. Generally, the electrochemical storage performance of a secondary battery can be improved by monitoring the composition and morphology of electrode materials. Because more is the intricacy of a nanostructured composite electrode material, more electrochemical storage applications would be expected. Despite the conventional methods suitable for practical production, the synthesis of metal‐organic frameworks (MOFs) would offer enormous opportunities for next‐generation battery applications by delicately systematizing the structure and composition at the molecular level to store sodium ions with larger sizes compared with lithium ions. Here in this review, we comprehensively discuss the progress of nanostructured MOFs and their derivatives applied as negative and positive electrode materials for effective sodium storage in SIBs. The commercialization goal has prompted the development of MOFs and their derivatives as electrode materials, before which the synthesis and mechanism for MOF‐based SIB electrodes with improved sodium storage performance were systematically discussed. Finally, the existing challenges, possible perspectives, and future opportunities will be anticipated.This article is protected by copyright. All rights reserved

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Section: Mof Derivatives As Sib Electrodesmentioning

confidence: 99%

Section: Mof Derivatives As Sib Electrodesmentioning

confidence: 99%

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Metal–Organic Framework‐Based Materials for Advanced Sodium Storage: Development and Anticipation

Zhou,

Reddy,

Zhong

et al. 2024

Advanced Materials

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“…The stability, safety, and reversibility have all improved with polyanionic compounds. , Because of its three-dimensional sodium mobility, excellent thermal stability, and quick ion conduction, Na 3 V 2 (PO 4 ) 3 (NVP) materials have drawn a lot attention among the polyanionic materials . NVP also offers a high redox voltage (3.4 V vs Na + /Na), an excellent theoretical energy density (almost 400 Wh/kg), and a little volume change as cathode for SIBs . However, NVP’s electrochemical performance is limited by its low intrinsic electrical conductivity. , …”

Section: Introductionmentioning

confidence: 99%

“…23 NVP also offers a high redox voltage (3.4 V vs Na + /Na), an excellent theoretical energy density (almost 400 Wh/kg), and a little volume change as cathode for SIBs. 24 However, NVP's electrochemical performance is limited by its low intrinsic electrical conductivity. 25,26 The low conductivity of NVP is often improved by surface treatment.…”

Section: Introductionmentioning

confidence: 99%

Na₃V₂(PO₄)₃ Cathode for Room-Temperature Solid-State Sodium-Ion Batteries: Advanced In Situ Synchrotron X-ray Studies to Understand Intermediate Phase Evolution

Pandit,

Johansen,

Susana Martínez-Cisneros

et al. 2024

Chem. Mater.

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Sodium-ion batteries (NIBs) can use elements that are abundantly present in Earth's crust and are technologically feasible for replacing lithium-ion batteries (LIBs). Hence, NIBs are essential components for sustainable energy storage applications. All-solid-state sodium batteries are among the most capable substitutes to LIBs because of their potential to have low price, great energy density, and consistent safety. Nevertheless, more advancements are needed to improve the electrochemical performance of the Na 3 V 2 (PO 4 ) 3 (NVP) cathode for NIBs, especially with regard to rate performance and operational lifespan. Herein, a core−shell NVP/C structure is accomplished by adopting a solid-state method. The initial reversible capacity of the NVP/C cathode is 106.6 mAh/g (current rate of C/10), which approaches the theoretical value (117.6 mAh/g). It also exhibits outstanding electrochemical characteristics with a reversible capacity of 85.3 mAh/g at 10C and a cyclic retention of roughly 94.2% after 1100 cycles. Using synchrotronbased operando X-ray diffraction, we present a complete examination of phase transitions during sodium extraction and intercalation in NVP/C. To improve safety and given its excellent ionic conductivity and broad electrochemical window, a Na superionic conductor (NASICON) solid electrolyte (Na 3.16 Zr 1.84 Y 0.16 Si 2 PO 12 ) has been integrated to obtain an all-solid-state NVP/C||Na battery, which provides an exceptional reversible capacity (95 mAh/g at C/10) and long-term cycling stability (retention of 78.3% after 1100 cycles).

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Recent Development of Phosphate Based Polyanion Cathode Materials for Sodium‐Ion Batteries

Ahsan,

Cai,

Wang

et al. 2024

Advanced Energy Materials

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Sodium‐ion batteries (SIBs) are regarded as next‐generation secondary batteries and complement to lithium‐ion batteries (LIBs) for large‐scale electrochemical energy storage applications due to the abundant availability, even distribution, and cost‐effectiveness of raw sodium resources. The phosphate‐based polyanions stand out of various cathode material owing to their high operation voltage, stable structure, superior safety, and excellent sodium‐storage properties. The undesirable electric conductivities and specific capacities limit their large‐scale industrialization. Herein, a recent research development of phosphate‐based polyanion cathodes including orthophosphate, oxyphosphate, pyrophosphate, and mixed phosphates is thoroughly reviewed. Subsequently, the effect of modification strategies including element doping, surface coating, morphology control, and electrode design toward high‐performance cathode materials for SIBs are systematically explored. Finally, the future research directions of phosphate‐based polyanion cathodes based on electrochemical performance including reversible capacity, voltage, energy density, rate capacity, cycling stability, and commercial applications are comprehensively concluded. It is believed that current review will present instructive perspectives into developing practicable phosphate‐based polyanion cathode materials for SIBs.

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Micro-nano Na3V2(PO4)3/C derived from metal-organic frameworks for high performance sodium ion batteries

Cited by 12 publications

References 37 publications

Metal–Organic Framework‐Based Materials for Advanced Sodium Storage: Development and Anticipation

Metal–Organic Framework‐Based Materials for Advanced Sodium Storage: Development and Anticipation

Na₃V₂(PO₄)₃ Cathode for Room-Temperature Solid-State Sodium-Ion Batteries: Advanced In Situ Synchrotron X-ray Studies to Understand Intermediate Phase Evolution

Recent Development of Phosphate Based Polyanion Cathode Materials for Sodium‐Ion Batteries

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Micro-nano Na3V2(PO4)3/C derived from metal-organic frameworks for high performance sodium ion batteries

Cited by 12 publications

References 37 publications

Metal–Organic Framework‐Based Materials for Advanced Sodium Storage: Development and Anticipation

Metal–Organic Framework‐Based Materials for Advanced Sodium Storage: Development and Anticipation

Na3V2(PO4)3 Cathode for Room-Temperature Solid-State Sodium-Ion Batteries: Advanced In Situ Synchrotron X-ray Studies to Understand Intermediate Phase Evolution

Recent Development of Phosphate Based Polyanion Cathode Materials for Sodium‐Ion Batteries

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Na₃V₂(PO₄)₃ Cathode for Room-Temperature Solid-State Sodium-Ion Batteries: Advanced In Situ Synchrotron X-ray Studies to Understand Intermediate Phase Evolution