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Cited by 63 publications
(32 citation statements)
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“…The two chelating rings adopt a trans arrangement around the iron atom. The two trans Fe-C carbene bonds of 2.076 and 2.094 Å for 1; 2.085 and 2.085 Å for 2 are indicative of a Fe-C single bond, and within the range of Fe-C carbene bond distances (1.74- [11][12][13][14]. The two trans Fe-O bond of 1.918 Å for 1, 1.9102 Å for 2 are very close to these found in a bis-ligand Fe(II) complex of N-isopropylsalicylaldimine (1.912, 1.916 Å ) [19], mostly due to the analogous bis-chelating structure of the two kinds of Fe(II) complexes.…”
Section: Crystal Structures Of 1 Andmentioning
confidence: 80%
See 1 more Smart Citation
“…The two chelating rings adopt a trans arrangement around the iron atom. The two trans Fe-C carbene bonds of 2.076 and 2.094 Å for 1; 2.085 and 2.085 Å for 2 are indicative of a Fe-C single bond, and within the range of Fe-C carbene bond distances (1.74- [11][12][13][14]. The two trans Fe-O bond of 1.918 Å for 1, 1.9102 Å for 2 are very close to these found in a bis-ligand Fe(II) complex of N-isopropylsalicylaldimine (1.912, 1.916 Å ) [19], mostly due to the analogous bis-chelating structure of the two kinds of Fe(II) complexes.…”
Section: Crystal Structures Of 1 Andmentioning
confidence: 80%
“…The first mononuclear NHC-Fe(II) halides, Fe(NHC) 2 X 2 , were synthesized in 2000 [11]. Since then, the piano-stool Fe(II) complexes of the type CpFe(CO) 2 (NHC)X [12] and pincer Fe(II)/Fe(III) complexes of Fe(2,6-bis(NHC)pyridine)X n (n = 2 or 3) [13] were reported by Siebert, Guerchais and Gibson et al, respectively. Very recently, binuclear NHC-Fe(II) complexes, [Fe 2 (l-S(CH 2 ) 3 S)(CO) 6Àx (NHC) x (x = 1, 2), were synthesized as bio-inspired derivatives by Capon et al [14].…”
Section: Introductionmentioning
confidence: 99%
“…Recently, Siebert et al [9,10] described the synthesis and characterization of the first anionic imidazol-2-ylidenes, the 3-borane-1-alkylimidazol-2-ylidenes anions and their metal complexes [11]. The first chelating tricarbene ligand with the topology of Trofimenko's tris(pyrazolyl)borates, tris(3-methylimidazolin-2-ylidene-1-yl)borate, has been introduced in 1995 by Fehlhammer and co-workers [12] together with its hexacarbene iron(III) and cobalt(III) complexes [13,14].…”
mentioning
confidence: 99%
“…Recently, Siebert et al [28,29] described the synthesis and characterization of the first anionic monocarbene imidazol-2-ylidenes, the 3-borane-1-alkylimidazol-2-ylidenes anions and their metal complexes [30]. The synthesis of monoanionic chelating dicarbene bis(imidazolylidene)borates, and their use as ligands in various homoleptic and heteroleptic palladium(II), platinum(II), gold(I) [31] and nickel(II) [32] complexes has been recently described.…”
Section: Introductionmentioning
confidence: 99%