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Cited by 198 publications
(68 citation statements)
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References 431 publications
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“…An unexpected conversion of [1] + into [2] 2 + , which involves substitution of chloride by CH 3 CN at the copper centre, has been observed in CH 3 CN/H 2 O mixtures. Surprisingly, formation of the acetonitrile complex does not occur in neat acetonitrile and requires the presence of water.…”
Section: H T U N G T R E N N U N G (Ch 3 Cn)s 4 H 3 -A C H T U N G T mentioning
confidence: 92%
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“…An unexpected conversion of [1] + into [2] 2 + , which involves substitution of chloride by CH 3 CN at the copper centre, has been observed in CH 3 CN/H 2 O mixtures. Surprisingly, formation of the acetonitrile complex does not occur in neat acetonitrile and requires the presence of water.…”
Section: H T U N G T R E N N U N G (Ch 3 Cn)s 4 H 3 -A C H T U N G T mentioning
confidence: 92%
“…During the course of this work a very interesting and unexpected conversion of cluster [1] + into [2] 2 + was observed in CH 3 CN/H 2 O mixtures, with formation of the acetonitrile complex [2] 2 + from [1] + being promoted by water. From a qualitative point of view, this reaction can be considered a new example of a process driven by solvation of the released chloride, [33][34][35] and a detailed experimental and theoretical study has been carried out with the aim of elucidating the kinetic and mechanistic features of this process.…”
Section: H T U N G T R E N N U N G (Ch 3 Cn)s 4 H 3 -A C H T U N G T mentioning
confidence: 93%
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“…CMF-4 has a rather large I-centered tetragonal unit cell (cell volume > 70 000 3 ) and is formed by 3D assembly of [Cd 17 S 4 (SPhMe-3) 28 ] 2À nanoclusters. Adjacent clusters are joined together through corner-sharing SPhMe-3 groups.…”
mentioning
confidence: 99%