2017
DOI: 10.37358/rc.17.1.5408
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Mesoionic 4-(2-Dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates

Abstract: New mesoionic 4-(2-dialkylamino-1,3-dithiol-2-ylium-4-yl)phenolates have been obtained from the corresponding 1,3-dithiolium salts under weak basic conditions. The 1,3-dithiolium salts have been synthesized by the cyclocondensation of 1-(4-hydroxyphenyl)-1-oxaethan-2-yl dithiocarbamates. The latter compounds have been obtained from the reaction of the 2-bromo-1-(4-hydroxyphenyl)ethan-1-one with various salts of dithiocarbamic acids. UV-Vis investigations proved the intramolecular charge transfer for the mesoio… Show more

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Cited by 8 publications
(7 citation statements)
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“…Resveratrol is a polyphenolic microconstituent that is formed in the skin of grapes in response to fungal attack of Botrytis cinerea, behaving like a phytoalexin, and the chemical structure has proven to be a 3,5.4'trihydroxystilbene [15,16,23].…”
Section: Resultsmentioning
confidence: 99%
“…Resveratrol is a polyphenolic microconstituent that is formed in the skin of grapes in response to fungal attack of Botrytis cinerea, behaving like a phytoalexin, and the chemical structure has proven to be a 3,5.4'trihydroxystilbene [15,16,23].…”
Section: Resultsmentioning
confidence: 99%
“…Ar-O band is between 3586 -3754 cm -1 and in the case of S-N rings is between1672 -1790 cm -1 . The band of valency vibration for C-N is at 1200 -1242 cm -1 being a very intense one [30][31][32][33].…”
Section: Structure Elucidation By Spectral Measurement Spectrum Irmentioning
confidence: 99%
“…The discovery of highly conductive organic charge transfer complexes which are formed from tetrathiafulvalenes derivatives and the acceptor tetracyano-p-quinodimethane has prompted interest in the discovery of new electron donors and acceptors which exhibit similar conductivity. [1][2][3][4] In general, charge-transfer [5][6][7][8][9][10][11][12][13][14][15] or push-pull [16][17][18][19][20] compounds have significant applications in the field of conducting materials. For these reasons heterocyclic compounds -especially those containing sulfur and nitrogen -represent an important resource for the material chemistry [21][22][23][24] and also for medicinal chemistry.…”
Section: Introductionmentioning
confidence: 99%