Merging Electron Deficient Boronic Centers with Electron-Withdrawing Fluorine Substituents Results in Unique Properties of Fluorinated Phenylboronic Compounds
Abstract:Fluorinated boron species are a very important group of organoboron compounds used first of all as receptors of important bioanalytes, as well as biologically active substances, including Tavaborole as an antifungal drug. The presence of substituents containing fluorine atoms increases the acidity of boronic compounds, which is crucial from the point of view of their interactions with analytes or certain pathogen’s enzymes. The review discusses the electron acceptor properties of fluorinated boronic species us… Show more
Fluorination of azopyridines regulates supramolecular bonding competition between [B ← N] adduct and co-crystal formation with phenylboronic acid catechol ester.
Fluorination of azopyridines regulates supramolecular bonding competition between [B ← N] adduct and co-crystal formation with phenylboronic acid catechol ester.
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