2021
DOI: 10.3390/membranes11110810
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Membrane-Based Electrolysis for Hydrogen Production: A Review

Abstract: Hydrogen is a zero-carbon footprint energy source with high energy density that could be the basis of future energy systems. Membrane-based water electrolysis is one means by which to produce high-purity and sustainable hydrogen. It is important that the scientific community focus on developing electrolytic hydrogen systems which match available energy sources. In this review, various types of water splitting technologies, and membrane selection for electrolyzers, are discussed. We highlight the basic principl… Show more

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Cited by 67 publications
(30 citation statements)
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References 152 publications
(254 reference statements)
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“…The most used PEMs are the Nafion™ and Nafion™-based membranes as a result of their high thermostability, high ionic conductivity, excellent chemical stability, good mechanical strength, and robustness at a low temperature during high levels of relative humidity [58]. There are, however, some major challenges associated with the use of the Nafion™, i.e., poor proton conductivity when temperatures are high under low humid environment and longer time needed for synthesis [58][59][60].…”
Section: Solid Oxide Water Electrolysismentioning
confidence: 99%
“…The most used PEMs are the Nafion™ and Nafion™-based membranes as a result of their high thermostability, high ionic conductivity, excellent chemical stability, good mechanical strength, and robustness at a low temperature during high levels of relative humidity [58]. There are, however, some major challenges associated with the use of the Nafion™, i.e., poor proton conductivity when temperatures are high under low humid environment and longer time needed for synthesis [58][59][60].…”
Section: Solid Oxide Water Electrolysismentioning
confidence: 99%
“…Currently, the energy consumption related to water electrolysis is 4.5–6.0 Kilowatt–hours per cubic meter (kWh/m 3 ) of H 2 when using water solution tanks (with an efficiency coefficient of around 60%) and 3.7–3.9 kWh/m 3 of H 2 when using solid polymer membrane electrolysis (efficiency coefficient of around 72–80%) [ 122 ]. However, the best and most effective modern hydrogen engines are capable of producing only 2.5–3 kWh from a single cubic meter of H 2 (recalculated to atmospheric pressure and 50–90 °C, which conditions are customary in water electrolysis) [ 123 ].…”
Section: Renewable Alternative Sources Of Energymentioning
confidence: 99%
“…The produced hydrogen may be directly injected into the natural gas fuel supply to combustion-based processes, through [73][74][75][76][77][78][79][80][81][82] Figure 4. Incorporation of hydrogen energy within an energy system with technologies to be analyzed in a plant scale.…”
Section: Electrolysismentioning
confidence: 99%