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Cited by 10 publications
(7 citation statements)
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“…Besides that, the final spectrum does not match the profile observed either for the species described by Dasgupta et al [49], or for the reducted nitrosilated analog [Ru 3 -O(CH 3 COO) 6 (4-pic) 2 NO] 0 , generated electrochemically [10]. In our case, despite the fact that the spectra changes very little, one can observe the onset of an absorption in between 800 and 1000 nm, characteristic of solvated species [Ru 3 O(CH 3 COO) 6 (L) 2 S] 0 .…”
Section: Photolysiscontrasting
confidence: 62%
See 1 more Smart Citation
“…Besides that, the final spectrum does not match the profile observed either for the species described by Dasgupta et al [49], or for the reducted nitrosilated analog [Ru 3 -O(CH 3 COO) 6 (4-pic) 2 NO] 0 , generated electrochemically [10]. In our case, despite the fact that the spectra changes very little, one can observe the onset of an absorption in between 800 and 1000 nm, characteristic of solvated species [Ru 3 O(CH 3 COO) 6 (L) 2 S] 0 .…”
Section: Photolysiscontrasting
confidence: 62%
“…Recently it was reported the reactivity of the analog [Ru 3 O(CH 3 COO) 6 (H 2 O) 3 ] + with ascorbic acid at pH 3.8 (acetate buffer) [49]. The authors have shown that the first reaction step occurs with the selective reduction of one Ru(III) ion concomitantly with the cleavage of one acetate bridge.…”
Section: Photolysismentioning
confidence: 99%
“…[9][10][11] It has been shown that mineral uptake by tissues is far better when the metal is in the form of a picolinato complex. Although the kinetics of analogous systems with some Ru III complexes have been examined in several laboratories, [14][15][16][17][18][19][20] the high electron-transfer rates and/or high reactivity of the ruthenium species in ligand displacement reactions have imposed severe limitations on the reaction conditions used. [10][11][12][13] The aim of this project was to gain further insight into the mechanism of the Ru III Ǟ Ru II transformation and to quantitatively compare the reactivity of the protolytic forms of l-ascorbic acid towards mer-[Ru(pic) 3 ].…”
Section: Introductionmentioning
confidence: 99%
“…Such studies include electron transfer reactions with biological reductants such as Lascorbic acid [1,9], application as electron mediators for water splitting [10], reactions in photoelectrochemical cells [11], radiolytic studies [12][13][14][15][16], and dichroism studies [17]. For many years, our research group and collaborators have been interested in studying the electron transfer reactions between small biological molecules and transition metal complexes [18][19][20][21][22][23][24][25][26][27], homogeneous catalysts [28] as well as developing electro-and photo-catalysts for the hydrogen production [29]. Some cobalt-containing complexes [6,7,12,16,30] (see Fig.…”
Section: Introductionmentioning
confidence: 99%