Mechanistic insight into the kinetic fragmentation of norpinonic acid in the gas phase: an experimental and density functional theory (DFT) study
Izabela Kurzydym,
Agata Błaziak,
Kinga Podgórniak
et al.
Abstract:Abstract. Norpinonic acid has been known as an important α-pinene atmospheric secondary organic aerosol (SOA) component. It is formed in the reaction of α-pinene, β-pinene or verbenone with atmospheric oxidizing reagents. In the presented study, tandem mass spectrometry techniques were used to determine the exact norpinonic acid fragmentation pathway in the gas phase. The precursor anion – deprotonated norpinonic acid (m/z 169), generated in an electrospray (ESI) source – was introduced into the collision cell… Show more
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