volume 104, issue 1-6, P299-308 1991
DOI: 10.1007/bf01245517
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Abstract: A basically new mechanism of the thermal decomposition of solids is proposed to explain the mass spectral observations of gaseous molecules of CoO, CuO, Cu20, NiO, PbO and Mg(OH)2 during the low-temperature decomposition of the anhydrous and hydrated nitrates of these metals. The mechanism consists of two stages: congruent gasification of all reaction products irrespective of their saturated vapor pressure and subsequent condensation of the lowvolatility species (oxides and hydroxides). The partial pressures …

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