High energy cosmic ray electrons plus positrons (CREs), which lose energy quickly during their propagation, provide an ideal probe of Galactic high-energy processes 1-7 and may enable the observation of phenomena such as dark-matter particle annihilation or decay [8][9][10] . The CRE spectrum has been directly measured up to ∼ 2 TeV in previous balloon-or spaceborne experiments [11][12][13][14][15][16] , and indirectly up to ∼ 5 TeV by ground-based Cherenkov γ-ray telescope arrays 17,18 . Evidence for a spectral break in the TeV energy range has been provided by indirect measurements of H.E.S.S. 17,18 , although the results were qualified by sizeable systematic uncertainties. Here we report a direct measurement of CREs in the energy range 25 GeV − 4.6 TeV by the DArk Matter Particle Explorer (DAMPE) 19 with unprecedentedly high energy resolution and low background. The majority of the spectrum can be properly fitted by a smoothly broken power-law model rather than a single power-law model. The direct detection of a spectral break at E ∼ 0.9 TeV confirms the evidence found by H.E.S.S., clarifies the behavior of the CRE spectrum at energies above 1 TeV and sheds light on the physical origin of the sub-TeV CREs.