The non-commuting graph, denoted by , is defined on a finite group , with its vertices are elements of excluding those in the center Β of . In this graph, two distinct vertices are adjacent whenever they do not commute in . The graph Β can be associated with several matrices including the most basic matrix, which is the adjacency matrix, , and a matrix called Sombor matrix, denoted by . The entries of Β are either the square root of the sum of the squares of degrees of two distinct adjacent vertices, or zero otherwise. Consequently, the adjacency and Sombor energies of Β is the sum of the absolute eigenvalues of the adjacency and Sombor matrices of , respectively, whereas the spectral radius of Β is the maximum absolute eigenvalues. Throughout this paper, we find the spectral radius obtained from the spectrum of Β and the Sombor energy of Β for dihedral groups of order , Β where . Moreover, there is an almost linear correlation between the Sombor energy and the adjacency energy of Β for Β which is slightly different than reported earlier in previous literature.