The chemically synthesized Fe x Pt 100−x nanoparticles with controlled compositions were annealed to transfer the disordered face-centered-cubic structure to the ordered structure. It was found that the L1 0 FePt structure can be formed in the wide compositional region of x = 40-68, and lower or higher Fe content leads to formation of the L1 2 FePt 3 or Fe 3 Pt phase, respectively. The Néel temperature of L1 2 FePt 3 phase and Curie temperatures ͑T C ͒ of L1 0 FePt and L1 2 Fe 3 Pt phases are all strongly composition dependent. The room-temperature saturation magnetization has an abnormal dependence on x which is caused by the low T C of Fe 3 Pt phase with x = 75-79. The big difference in T C between the heating and cooling thermomagnetic curves of the Fe-Pt alloys with x =79-90 can be attributed to the difference of ␣ ⇔ ␥ phase transition temperature during heating and cooling. On the other hand, T C of the L1 0 FePt nanoparticles was found to be strongly size dependent.