2017
DOI: 10.1039/c7dt00823f
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Magnesium porphyrins with relevance to chlorophylls

Abstract: A review on the chemistry of magnesium porphyrins, which have significant interest owing to the relevance to chlorophyll molecules, is presented with emphasis on bicarbonate adducts of magnesium porphyrin and chlorophyll. The chemistry of 26 unique magnesium porphyrins is described as review articles on synthetic magnesium porphyrins are limited. Interest is given to the electron transfer reactions of magnesium porphyrins in artificial photosynthetic systems. The magnesium porphyrins are described considering … Show more

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Cited by 53 publications
(34 citation statements)
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“…35 The chlorophyll b was puried by silica gel column chromatography. [36][37][38] The following mobile phases were applied with the order of: 60% n-hexane, 16% cyclohexane, 10% ethyl acetate, 10% acetone, and 4% methanol. The elution order using this elution solvent system was bcarotene, chlorophyll b, and xanthophyll (from top to bottom).…”
Section: Demetalation Of Chlorophyll B (2)mentioning
confidence: 99%
“…35 The chlorophyll b was puried by silica gel column chromatography. [36][37][38] The following mobile phases were applied with the order of: 60% n-hexane, 16% cyclohexane, 10% ethyl acetate, 10% acetone, and 4% methanol. The elution order using this elution solvent system was bcarotene, chlorophyll b, and xanthophyll (from top to bottom).…”
Section: Demetalation Of Chlorophyll B (2)mentioning
confidence: 99%
“…For example, iron porphyrins are efficient and highly selective catalysts [39,40]. Magnesium porphyrins play a key role in photosynthesis in plant cells [41]. Chlorin e6 is a hydrophilic photosensitizers with structure similar to porphyrin [42].…”
Section: Discussionmentioning
confidence: 99%
“…A further increase of Ce supplementation recovered Mg levels to that observed in the control sample. Magnesium cation coordinated with the porphyrin ring forms the chlorophyll active site [106,107]. It is also crucial for the activity of RuBisCO, and finally, the C3 carbon fixation pathway [108][109][110].…”
Section: Plant Uptake and Accumulation Of Mineral Nutrientsmentioning
confidence: 99%