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“…[19] Pyridinium CILs with axial chirality (XI) have been synthesized through an enantioselective reaction, [11] while other pyridinium derivatives have the chirality residing in the alkyl substituent (XII). [20] Oxazolium salts (XIII) [18] have been derived from (S)-valine on a multigram scale and thiazolium CILs (XIV) [21] have been obtained from amino alcohols.…”
Section: Introductionmentioning
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“…[19] Pyridinium CILs with axial chirality (XI) have been synthesized through an enantioselective reaction, [11] while other pyridinium derivatives have the chirality residing in the alkyl substituent (XII). [20] Oxazolium salts (XIII) [18] have been derived from (S)-valine on a multigram scale and thiazolium CILs (XIV) [21] have been obtained from amino alcohols.…”
Section: Introductionmentioning
“…Following structural motif (a) Ujiie synthesized the first ILC with tilted mesophase by reacting a neutral azobenzene aminoalcohol with tartaric acid (Scheme 21). [182] The SmC phase already present in the neutral aminoalcohol changes to a chiral SmC* phase, while the temperature range remains unaffected [183] . Later, Ujiie reported that SmC phases can be induced in structurally related azobenzene aminoalcohols by protonation with HI [184]…”
Section: Rare Ilc Phasesmentioning
“… Conversion of neutral azobenzene aminoalcohol 44 into ionic derivative 45 by treatment with tartaric acid introduced by Ujiie resulting in the first tilted mesophase ILC . [183] …”
Section: Rare Ilc Phasesmentioning
“…We addressed also the formation of chiral mesophases due to the presence of the chiral camphorsulfonamide groups. In fact, examples of chiral ionic liquid crystals (ILCs) are scarce, and among the few examples reported in the literature [46][47][48][49][50], only one example reported the formation of chiral mesophases [51].…”
Section: Introductionmentioning