Hereunder, we study the class of irreducible private states that are private states from which all the secret content is accessible via measuring their key part. We provide the first protocol which distills key not only from the key part, but also from the shield if only the state is reducible. We prove also a tighter upper bound on the performance of that protocol, given in terms of regularized relative entropy of entanglement instead of relative entropy of entanglement previously known. This implies in particular that the irreducible private states are all strictly irreducible if and only if the entangled but key-undistillable states ('entangled key-undistilable states') exist. In turn, all the irreducible private states of the dimension 4⊗4 are strictly irreducible, that is, after an attack on the key part they become separable. Provided the bound key states exist, we consider different subclasses of the irreducible private states and their properties. Finally we provide a lower bound on the trace norm distance between key-undistillable states and private states, in sufficiently high dimensions.Obtaining the classical secret key for data encryption via quantum states is one of the main contributions of quantum information theory towards security in the era of information [1]. This goal has been achieved using the celebrated maximally entangled state [2][3][4]. However, the quantum states which have a property that after the measurement one can get at least m bits of a secret secure key (against quantum eavesdropper) form a much broader class of states called private states [5]. The maximally entangled state is an example of a private state. In general, a private state has two subsystems: the key part (AB) and the shield (A B ¢ ¢). From the key part one can obtain the secure key via von Neumann measurements on its local subsystems, while the shield is protecting the key part from the Eavesdropper who holds the purifying system of the total state. More precisely, any private state with at least m bits of key has the form Private states have been used to formalize quantitative relation between secrecy and entanglement. Namely, it has been shown that the classical secure key, is in, fact an entanglement measure denoted as K D [5,6]. This led to upper bounds on the secure content of quantum states via relative entropy of entanglement [5][6][7] and squashed entanglement [8][9][10][11] and further generalizations for quantum channels via squashed entanglement of a quantum channel [12,13] and relative entropy of entanglement extended to quantum channel [14] (see also [15][16][17][18] in this context). Recently, there has been shown a related impossibility result that one cannot achieve non-negligible amount of key [19] in the framework of quantum repeaters [20] using some certain approximate private states (a problem of quantum key-repeaters).In general the importance of the class of private states follows from the fact that any quantum key distribution protocol (including the so-called quantum device indep...