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“…In photochemical transformation (process 1), incident light may penetrate the product and reach photoreactive ENM, inducing excitation ENM [14,15] and generation of free radicals [16] or by direct interaction with other components of the product [17]. The extent to which this process will influence the creation of PW-ENM (or possibly ET-ENM) is related to the incident light wavelength, the capacity of the light to penetrate the product and the outer layers of the ENM (for example, aggregated or surface-coated particles may have lower light penetration efficiency), and the capacity of the photosensitive portion of the ENM to be excited or photodegraded.…”
Section: Fate and Transformation Processesmentioning
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“…In photochemical transformation (process 1), incident light may penetrate the product and reach photoreactive ENM, inducing excitation ENM [14,15] and generation of free radicals [16] or by direct interaction with other components of the product [17]. The extent to which this process will influence the creation of PW-ENM (or possibly ET-ENM) is related to the incident light wavelength, the capacity of the light to penetrate the product and the outer layers of the ENM (for example, aggregated or surface-coated particles may have lower light penetration efficiency), and the capacity of the photosensitive portion of the ENM to be excited or photodegraded.…”
Section: Fate and Transformation Processesmentioning
“…The third strategy is to exploit scaling laws and specific effects at the nanoscale [53][54][55][56] to overcome the limiting problems of metal oxide absorbers, such as their short electron-hole lifetimes and low mobility. This nanostructuring strategy has gained significant interest in the last 20 years [57][58][59][60][61][62][63][64][65][66][67] and is the focus of this chapter.…”
Section: Photoelectrochemical Water Splitting As a Pathway To Sustainmentioning
“…12) is more difficult to achieve than in the bulk because at average doping concentrations (n 0 ¼ 10 17 cm À3 ) space charge layers are not effective on the nanoscale [30,59,158,159]. Also, for (Fig.…”
Section: Electron-hole Separationmentioning
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