2016
DOI: 10.1038/nnano.2016.32
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Abstract: Metallic lithium is a promising anode candidate for future high-energy-density lithium batteries. It is a light-weight material, and has the highest theoretical capacity (3,860 mAh g(-1)) and the lowest electrochemical potential of all candidates. There are, however, at least three major hurdles before lithium metal anodes can become a viable technology: uneven and dendritic lithium deposition, unstable solid electrolyte interphase and almost infinite relative dimension change during cycling. Previous research… Show more

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Cited by 1,566 publications
(953 citation statements)
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References 52 publications
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“…Molten lithium infusion was developed for pre‐storing lithium into the lithiophilic interlayer spacing of the sparked rGO. Such anode exhibited low dimension variation (≈20%) during cycling and good mechanical flexibility 53. To create a lithium composite nanostructured lithium metal anode, Cui's group has introduced a facile melt‐infusion approach to effectively encapsulate lithium inside a porous carbon scaffold with Si coated lithiophilic layer (Figure 3b).…”
Section: Conductive Micro/nanostructured Frameworkmentioning
confidence: 99%
See 1 more Smart Citation
“…Molten lithium infusion was developed for pre‐storing lithium into the lithiophilic interlayer spacing of the sparked rGO. Such anode exhibited low dimension variation (≈20%) during cycling and good mechanical flexibility 53. To create a lithium composite nanostructured lithium metal anode, Cui's group has introduced a facile melt‐infusion approach to effectively encapsulate lithium inside a porous carbon scaffold with Si coated lithiophilic layer (Figure 3b).…”
Section: Conductive Micro/nanostructured Frameworkmentioning
confidence: 99%
“…a) Fabrication of the layered Li‐rGO composite film. Reproduced with permission 53. Copyright 2016, Nature Publishing Group.…”
Section: Conductive Micro/nanostructured Frameworkmentioning
confidence: 99%
“…Benefiting from the highly conductive surface area, stable electrolyte/electrode interface, and negligible volume fluctuation, the carbon framework encapsulated with Li (labeled as Li/C) can operate for more than 80 cycles under a high current rate of 3 mA cm −2 . Later, conductive rGO [339], Ni foam [340], and channel guided carbon [341] were also proposed as 3D lithiophilic scaffolds for lithium infusion due to the alloying reactions and lithiophilic surfaces. Recently, a nanoporous Li x Si-Li 2 O composite with high ionic conductivity was obtained via mixing over stoichiometric amounts of molten Li and submicrometer-sized SiO powder at high temperature [342].…”
Section: A 3d Lithium Depositionmentioning
confidence: 99%
“…A remarkable instance is Li infused into a high lithiophilicity, reduced graphene oxide film (rGO) with uniform nanogaps. [37] Through a "spark" reaction between the densely stacked GO film and molten Li, the rGO film with a uniform layered nanostructure consisted of expanding nanogaps was obtained (Figure 4b-d). Owning to the synergetic effects of the lithiophilic nature of sparked rGO and the capillary force produced by the nanogaps, Li is homogeneously infused into the interlayer spacing (Figure 4e).…”
Section: Graphene As LI Metal Hostmentioning
confidence: 99%