Kinetics of the electroreduction of Co(salen) in DMSO

Brisard, Gessie; Manzini, M.; Lasia, Andrzej

doi:10.1016/0022-0728(92)80518-9

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Electrochemistry Of Coii(salen) In Dmf Containing Other Elec...1

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Cited by 6 publications

(1 citation statement)

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“…in solvents such as DMF.36 The values found are, however, igher by a factor of B100 than those reported in earlier papers. 35,37 The discrepancy arises because the earlier workers assumed that cations do not interact with R 4 NC oI(salen)~; this is clearly incorrect. It was also considered of interest to investigate the extent to which reaction (VI) is more correctly written…”

Section: Electrochemistry Of Coii(salen) In Dmf Containing Other Elec...mentioning

confidence: 99%

Influence of electrolyte concentration on coupled chemical reactions Part 1Reduction of CoII(salen)in aprotic solvents

Pletcher¹,

Thompson²

1997

Faraday Trans.

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Section: Electrochemistry Of Coii(salen) In Dmf Containing Other Elec...mentioning

confidence: 99%

Influence of electrolyte concentration on coupled chemical reactions Part 1Reduction of CoII(salen)in aprotic solvents

Pletcher¹,

Thompson²

1997

Faraday Trans.

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Electrochemical Reactions in Nonaqueous and Mixed Solvents

Galus

1995

Advances in Electrochemical Sciences and Engineering

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Elektrochemie mit Ultramikroelektroden

Heınze

1993

Angewandte Chemie

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Nach den grundlegenden Entwicklungen elektrochemischer Methoden in den fiinfziger und sechziger Jahren, die unter anderem die Voltammetrie und Kleinsignaltechniken betrafen, zeichnen sich rnit der Entdeckung der ungewohnlichen Eigenschaften von Ultramikroelektroden wieder neue Perspektiven zur Analyse von Elektrodenprozessen ab. Die bislang wenig beachtete Tatsache, daD an extrem kleinen Elektroden aufgrund veranderter Massentransportbedingungen aul3erordentlich hohe Stromdichten auftreten, die Strome selbst aber sehr klein werden, fiihrt zu einer Fiille von elektroanalytischen Anwendungen, die rnit konventionellen Elektroden nicht moglich sind. Besonders hervorzuheben sind Experimente in nahezu elektrolytfreien Losungen, in unpolaren Losungsmitteln, im Festkorper und sogar in der Gasphase. Die bei kleinen Vorschubgeschwindigkeiten durch die GroRe der Elektrode veranderte MeDzeitskala und komplementar hierzu die geringen iR-Effekte bei sehr hohen Vorschubgeschwindigkeiten ermoglichen zudem die Untersuchung sehr schneller homogener und heterogener Elektrodenprozesse.

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Kinetics of the electroreduction of Co(salen) in DMSO

Cited by 6 publications

References 20 publications

Influence of electrolyte concentration on coupled chemical reactions Part 1Reduction of CoII(salen)in aprotic solvents

Influence of electrolyte concentration on coupled chemical reactions Part 1Reduction of CoII(salen)in aprotic solvents

Electrochemical Reactions in Nonaqueous and Mixed Solvents

Elektrochemie mit Ultramikroelektroden

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