1997
DOI: 10.1006/jcat.1997.1467
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Kinetics and Selectivity of 2-Propanol Conversion on Oxidized Anatase TiO2

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Cited by 104 publications
(101 citation statements)
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“…In spite of that, we just identified the olefin over either of aforementioned TiO 2 phases. It seemed that operating conditions could exert a major effect on observed discrepancies, as Rekoske et al [29] showed strong selectivity dependence (in aforementioned reaction over different titania phases) on several operating parameters (reaction temperature, alcohol partial pressure, type of gas carrier, etc. ), concluding then that selectivity could be compared just for experiments carried out under similar conditions.…”
Section: Isopropanol Dehydrationmentioning
confidence: 96%
“…In spite of that, we just identified the olefin over either of aforementioned TiO 2 phases. It seemed that operating conditions could exert a major effect on observed discrepancies, as Rekoske et al [29] showed strong selectivity dependence (in aforementioned reaction over different titania phases) on several operating parameters (reaction temperature, alcohol partial pressure, type of gas carrier, etc. ), concluding then that selectivity could be compared just for experiments carried out under similar conditions.…”
Section: Isopropanol Dehydrationmentioning
confidence: 96%
“…It has been shown that this reaction could take place by using clays as catalysts [30,31], and in fact, it has been used by various researchers in order to monitor the catalytic behavior of acidic surfaces [32][33][34]. However, this reaction has never been achieved by using tungsten doped materials due to the surface acidity required.…”
Section: Gas-phase Catalysismentioning
confidence: 98%
“…However, it has been proved [1] that dehydrogenation to acetone over the catalysts based on metal oxides occurs also on the redox centres. Some reports show that dehydrogenation and dehydration of isopropanol are not only determined by surface acidic or basic properties of catalyst but also strongly affected by the reaction conditions employed, such as reaction temperature, isopropanol partial pressure and the oxidizing nature of the carrier gas [9,10]. Despite the above presented ambiguities in the course of the reaction, the decomposition of isopropanol is assumed a useful method of investigation.…”
Section: Introductionmentioning
confidence: 98%