2009
DOI: 10.1021/es902666y
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Abstract: Rate constants for the gas-phase reactions of the OH radical with 1,4-butanediol,4-hydroxybutanal, and 3-hydroxypropanalwere measured at 298 +/- 2 K and atmospheric pressure using a relative rate technique and with 4-hydroxybutanal and 3-hydroxypropanal being formed in situ from the OH + 1,4-butanediol reaction, and were (in units of 10(-11) cm(3) molecule(-1) s(-1)) 3.67 +/- 0.31, 3.0(-1.0)(+1.5), and 3.5(-1.0)(+1.3), respectively, with the latter being a lower limit because of the possibility of second-gener… Show more

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