J. Polym. Sci. A Polym. Chem.
 1998
DOI: 10.1002/(sici)1099-0518(19981130)36:16<2905::aid-pola9>3.0.co;2-9
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Kinetic and ESR studies on radical polymerization of methyl methacrylate in the presence of fullerene

Makiko Seno
1
,
Hironori Fukunaga
2
,
Tsuneyuki Sato
3
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Cited by 40 publications

(19 citation statements)
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“…This radical was not observed in the absence of C 60 . The observed spectrum ( g ‐value = 2.003) is nearly same as that of the fullerene radical (C 60 •) formed in the MMA polymerization with MAIB as reported previously 19. So, the spectrum is assignable to fullerene radical derived from the reaction of C 60 with poly(VAc) radicals or the primary radicals from MAIB.…”
Section: Resultssupporting
confidence: 82%
Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.
“…This radical was not observed in the absence of C 60 . The observed spectrum ( g ‐value = 2.003) is nearly same as that of the fullerene radical (C 60 •) formed in the MMA polymerization with MAIB as reported previously 19. So, the spectrum is assignable to fullerene radical derived from the reaction of C 60 with poly(VAc) radicals or the primary radicals from MAIB.…”
Section: Resultssupporting
confidence: 82%
Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.
“…Thus, MBOIA served as a retarder for St, a conjugative electron‐rich monomer, and as an inhibitor for VAc, a nonconjugative monomer, whereas it displayed little effect on the polymerization of MMA, a conjugative electron‐deficient monomer. Similar behaviors were also observed for other retarders such as nitrobenzene9 and fullerene(C 60 ) 10–12…”
Section: Resultssupporting
confidence: 78%
“…To obtain the R i value ( R i = 2 k d f [MAIB]), k d f was determined under the polymerization conditions without MBOIA with radical trapping with TEMPO, as described in a previous article 10. MAIB decomposes into 1‐methyl‐1‐methoxycarbonylethyl radicals as a primary radical and nitrogen.…”
Section: Resultsmentioning
confidence: 99%
Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.
“…These results suggest that the MDMO‐PPV singlet state is involved in the photo‐chemical aging. Moreover, the radical scavenging properties of fullerene and its derivatives are well‐known 26–31. Therefore, the slowdown of the MDMO‐PPV degradation in the presence of PCBM could also be linked to the radical scavenging properties of PCBM.…”
Section: Resultsmentioning
confidence: 99%
Exaggerated anticipatory anxiety is common in social anxiety disorder (SAD). Neuroimaging studies have revealed altered neural activity in response to social stimuli in SAD, but fewer studies have examined neural activity during anticipation of feared social stimuli in SAD. The current study examined the time course and magnitude of activity in threat processing brain regions during speech anticipation in socially anxious individuals and healthy controls (HC). Method Participants (SAD n = 58; HC n = 16) underwent functional magnetic resonance imaging (fMRI) during which they completed a 90s control anticipation task and 90s speech anticipation task.
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