Janus Mesoporous Sensor Devices for Simultaneous Multivariable Gases Detection

Wang, Ruicong; Lan, Kun; Chen, Zheng; Zhang, Xingmiao; Hung, Chin‐Te; Zhang, Wei; Wang, Changyao; Wang, Shuai; Chen, Aibing; Li, Wei; Xu, Xin; Zhao, Dongyuan

doi:10.1016/j.matt.2019.07.004

Cited by 49 publications

(44 citation statements)

References 40 publications

(39 reference statements)

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“…For O 1 s (Figure S6f), three peaks are assigned to 532.4 eV, 533.2 eV and 533.8 eV for the binding energy of O−C=O, −OH and C−O−C=O bond, respectively [23] . From the analysis of XPS, it is evident that the ‐COOH were formed on the surface of mesoporous carbon because of the oxidation of resol‐based phenolic resins during pyrolysis, [24] which leads to higher surface charge and pH‐sensitive performance. The result of Fourier Transform Infrared (FT‐IR, Figure S8) is consistent with the XPS analysis, indicating the MCS nanocomposite membranes have “reinforced concrete”‐structured frameworks.…”

Section: Resultsmentioning

confidence: 98%

Interfacial Super‐Assembly of Ordered Mesoporous Carbon‐Silica/AAO Hybrid Membrane with Enhanced Permselectivity for Temperature‐ and pH‐Sensitive Smart Ion Transport

Zhou

Xie

et al. 2021

Angew Chem Int Ed

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Nanofluidic devices have been widely used for diode‐like ion transport and salinity gradients energy conversion. Emerging reverse electrodialysis (RED) nanofluidic systems based on nanochannel membrane display great superiority in salinity gradient energy harvesting. However, the imbalance between permeability and selectivity limits their practical application. Here, a new mesoporous carbon‐silica/anodized aluminum (MCS/AAO) nanofluidic device with enhanced permselectivity for temperature‐ and pH‐regulated energy generation was obtained by interfacial super‐assembly method. A maximum power density of 5.04 W m−2 is achieved, and a higher performance can be obtained by regulating temperature and pH. Theoretical calculations are further implemented to reveal the mechanism for ion rectification, ion selectivity and energy conversion. Results show that the MCS/AAO hybrid membrane has great superiority in diode‐like ion transport, temperature‐ and pH‐regulated salinity gradient energy conversion.

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Section: Resultsmentioning

confidence: 98%

Interfacial Super‐Assembly of Ordered Mesoporous Carbon‐Silica/AAO Hybrid Membrane with Enhanced Permselectivity for Temperature‐ and pH‐Sensitive Smart Ion Transport

Zhou

Xie

et al. 2021

Angew Chem Int Ed

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“…[22] ForO1s (Figure S6f), three peaks are assigned to 532.4 eV,533.2 eV and 533.8 eV for the binding energy of OÀ C=O, ÀOH and CÀOÀC=Ob ond, respectively. [23] From the analysis of XPS,itisevident that the -COOH were formed on the surface of mesoporous carbon because of the oxidation of resol-based phenolic resins during pyrolysis, [24] which leads to higher surface charge and pH-sensitive performance.T he result of Fourier Transform Infrared (FT-IR, Figure S8) is consistent with the XPS analysis,i ndicating the MCS nanocomposite membranes have "reinforced concrete"-structured frameworks.T his special structure and super-assembly interaction can improve thermal stability,c hemical conductivity, and mechanical properties of membrane. [25] Thee xisting of hydrophobic region originating from polymer endows MCS/ AAOw ith special temperature-dependent ion transport.…”

Section: Methodsmentioning

confidence: 99%

Interfacial Super‐Assembly of Ordered Mesoporous Carbon‐Silica/AAO Hybrid Membrane with Enhanced Permselectivity for Temperature‐ and pH‐Sensitive Smart Ion Transport

Zhou

Xie

et al. 2021

Angewandte Chemie

View full text Add to dashboard Cite

Nanofluidic devices have been widely used for diode-like ion transport and salinity gradients energy conversion. Emerging reverse electrodialysis (RED) nanofluidic systems based on nanochannel membrane displayg reat superiority in salinity gradient energy harvesting.H owever, the imbalance between permeability and selectivity limits their practical application. Here,anew mesoporous carbon-silica/ anodized aluminum (MCS/AAO) nanofluidic device with enhanced permselectivity for temperature-and pH-regulated energy generation was obtained by interfacial super-assembly method. Amaximum power density of 5.04 Wm À2 is achieved, and ah igher performance can be obtained by regulating temperature and pH. Theoretical calculations are further implemented to reveal the mechanism for ion rectification, ion selectivity and energy conversion. Results show that the MCS/AAOh ybrid membrane has great superiority in diodelike ion transport, temperature-and pH-regulated salinity gradient energy conversion.

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“…Because of large pore sizes, high surface areas, and tunable architectures, [ 17–19 ] mesoporous materials have been demonstrated promising performances in a wide range of applications, [ 20–28 ] such as, catalysis, energy storage, biomedicines, superconductors, and sensing. Specifically, mesoporous materials are ideal supports for functional nanoparticles.…”

Section: Introductionmentioning

confidence: 99%

Recent Advances in the Marriage of Catalyst Nanoparticles and Mesoporous Supports

Zhang

Zhu

Ren

et al. 2021

Adv Materials Inter

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The marriage of catalyst nanoparticles and mesoporous supports brings exciting new opportunities in the field of catalysis, which provides the ability to create advanced nanoporous catalysts for a wide range of catalytic processes. It has been found that not only the features of mesoporous supports, such as, surface areas, mesostructures, and pore sizes, are critical for the catalytic performances, but also the unique properties of catalyst nanoparticles, including dispersion, particle size, and loading amount, play critical roles in determining catalytic performance. Those aspects have been discussed partly in previous reviews, but a comprehensive overview on the basic design principles and synthetic methods for the marriage of catalyst nanoparticles and mesoporous supports is still lacking. In this review, the recent progresses in the fabrication of advanced catalysts by incorporation of catalyst nanoparticles into mesoporous supports are summarized. First, the synthetic strategies for the controllable synthesis are reviewed. At the same time, the corresponding chemical‐/physically properties of the resultant supported mesoporous catalysts are highlighted. After that, the catalytic performances of the resultant mesoporous catalysts in the thermal catalysis, photocatalysis, and electrocatalysis are discussed. Moreover, the research challenges and perspectives in this field are assessed.

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Janus Mesoporous Sensor Devices for Simultaneous Multivariable Gases Detection

Cited by 49 publications

References 40 publications

Interfacial Super‐Assembly of Ordered Mesoporous Carbon‐Silica/AAO Hybrid Membrane with Enhanced Permselectivity for Temperature‐ and pH‐Sensitive Smart Ion Transport

Interfacial Super‐Assembly of Ordered Mesoporous Carbon‐Silica/AAO Hybrid Membrane with Enhanced Permselectivity for Temperature‐ and pH‐Sensitive Smart Ion Transport

Interfacial Super‐Assembly of Ordered Mesoporous Carbon‐Silica/AAO Hybrid Membrane with Enhanced Permselectivity for Temperature‐ and pH‐Sensitive Smart Ion Transport

Recent Advances in the Marriage of Catalyst Nanoparticles and Mesoporous Supports

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