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Cited by 78 publications
(88 citation statements)
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“…The species were identified using rotationally-resolved infrared spectroscopy to reveal polar structures in slipped-parallel geometries. A further study of two isotopologues of (N 2 O) 2 by rotationally-resolved infrared spectroscopy has since allowed a more complete determination of the molecular structure [21]. The determined parameters are in agreement with the results of a recent ab initio study [22].…”
Section: Introductionsupporting
confidence: 83%
See 1 more Smart Citation
“…The species were identified using rotationally-resolved infrared spectroscopy to reveal polar structures in slipped-parallel geometries. A further study of two isotopologues of (N 2 O) 2 by rotationally-resolved infrared spectroscopy has since allowed a more complete determination of the molecular structure [21]. The determined parameters are in agreement with the results of a recent ab initio study [22].…”
Section: Introductionsupporting
confidence: 83%
“…Owing to the limited quantity of available sample, measurements were focussed on selected transitions that allowed key parameters to be determined. The use of a gas sample containing >95% helium has previously been found to be essential for the observation of polar dimers of OCS and N 2 O [19][20][21]23].…”
Section: Methodsmentioning
confidence: 99%
“…All the spectra were recorded by direct absorption using a rapid-scan tuneable diode laser spectrometer at The University of Calgary, as described previously [33][34][35][36]. Wavenumber calibration was ensured by simultaneously recording signals from a fixed etalon and a room temperature reference gas cell, which was usually filled with CO 2 or N 2 O. Spectra were assigned, simulated, and fitted using Colin Western's computer program PGOPHER [37].…”
Section: Introductionmentioning
confidence: 99%
“…The experiments are performed using a pulsed supersonic jet expansion of a dilute mixture of OCS and C 2 H 2 in helium carrier gas. Spectra are observed by direct absorption using a tunable diode laser, [5][6][7][8] and simulated using Colin…”
Section: Introductionmentioning
confidence: 99%