Isothermal Vapor−Liquid Equilibria, Excess Molar Enthalpies, and Excess Molar Volumes of Trichloromethane + 1,2-Epoxybutane at (288.15, 298.15, and 313.15) K

Abstract

Isothermal vapor−liquid equilibria, VLE, excess Gibbs energies, , excess molar enthalpies, , and excess molar volumes, , were determined for the binary mixture trichloromethane + 1,2-epoxybutane at (288.15, 298.15, and 313.15) K and at atmospheric pressure. All excess properties are negative. The vapor−liquid equilibrium data are thermodynamically consistent and have been fitted to the Redlich−Kister equation. The influence of temperature has been discussed, and the relative magnitudes and signs of the excess properties have been outlined in terms of molecular interactions. Smooth representations of the results are presented.

Densities and Excess Molar Volumes of the Ternary Mixture 2-Butanol + Chloroform + Benzene and Binary Mixtures 2-Butanol + Chloroform, or + Benzene over the Temperature Range (288.15 to 313.15) K

“…), chloroform (stabilized with amylene) by Riedel-de Haën with a purity of 99.8 mass %, and benzene by Aldrich with a purity of 99.9 mass % (HPLC). Table lists the measured densities of 2-butanol, chloroform, and benzene, which agree to within ± 0.07 kg·m −3 with most of the corresponding literature values. – …”

“…Table 1 lists the measured densities of 2-butanol, chloroform, and benzene, which agree to within ( 0.07 kg • m -3 with most of the corresponding literature values. [10][11][12][13] Measurements. Densities F of the ternary and binary mixtures and corresponding pure substances were measured by means of an Anton Paar DMA 5000 digital vibrating U-tube densimeter (with automatic viscosity correction) having a stated accuracy ( 5 • 10 -3 kg • m -3 .…”

Temperature Dependence of Densities and Excess Molar Volumes of the Ternary Mixture (1-Butanol + Chloroform + Benzene) and its Binary Constituents (1-Butanol + Chloroform and 1-Butanol + Benzene)

“…), chloroform (stabilized with amylene) by Riedel-de Haën with a purity of 99.8 mass%, while benzene by Aldrich with a purity of 99.9 mass% (HPLC). Table 1 lists the measured densities [17] of the pure components at 298.15, and they agree within ±4 × 10 −5 g · cm −3 with most of the corresponding literature values [17,18].…”

Densities and Excess Molar Volumes of the Binary 1-Propanol + Chloroform and 1-Propanol + Benzene and Ternary 1-Propanol + Chloroform + Benzene Mixtures at (288.15, 293.15, 298.15, 303.15, 308.15, and 313.15) K

“…Chloroform (stabilized with amylene) was supplied by Riedel-de Haën with a purity of 99.8 %, and benzene was supplied by Aldrich with a purity of 99.9 % (HPLC). Table lists the measured densities of 1-propanol, chloroform, and benzene, which agree to within ± 0.09 kg·m -3 with most of the corresponding literature values. − …”