Iron-based metal-organic framework: Synthesis, structure and current technologies for water reclamation with deep insight into framework integrity

Joseph, Jessy; Iftekhar, Sidra; Srivastava, Varsha; Fallah, Zari; Zare, Ehsan Nazarzadeh; Sillanpää, Mika

doi:10.1016/j.chemosphere.2021.131171

Cited by 114 publications

(48 citation statements)

References 268 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In addition, Ti is one of the most essential metals in photocatalytic systems. In particular, Ti-based metal-organic frameworks have great potential for photocatalytic reactions, including CO 2 reduction, N 2 fixation, H 2 O 2 production, H 2 generation, environmental remediation of organic and inorganic pollutants, and organic transformation reactions, owing to their low toxicity, high abundance in the earth's crust, excellent optical properties, and unique structures [116]. 3D Ti MOFs have been synthesized and characterized.…”

Section: Synthesis Of Iron and Titanium-based 2dmentioning

confidence: 99%

Recent Advances and New Challenges: Two-Dimensional Metal–Organic Framework and Their Composites/Derivatives for Electrochemical Energy Conversion and Storage

Nivetha

Sharma

Jana

et al. 2023

International Journal of Energy Research

View full text Add to dashboard Cite

Metal–organic frameworks (MOFs), as a new generation of intrinsically porous extended crystalline materials formed by coordination bonding between the organic ligands and metal ions or clusters, have attracted considerable interest in many applications owing to their high porosity, diverse structures, and controllable chemical structure. Recently, 2D transition-metal- (TM-) based MOFs have become a hot topic in this field because of their high aspect ratio derived from their large lateral size and small thickness, as well as the advantages of MOFs. Moreover, 2D TM-based MOFs can act as good precursors to construct heterostructures with high electrical conductivity and abundant active sites for a range of applications. This review comprehensively introduces the widely adopted synthesis strategies of 2D TM-based MOFs and their composites/derivatives. In addition, this paper summarizes and highlights the recent advances in energy conversion and storage, including the hydrogen evolution reaction, oxygen evolution reaction, oxygen reduction reaction, CO2 reduction reaction, urea oxidation reaction, batteries, and supercapacitors. Finally, the challenges in developing these intriguing 2D layered materials and their composites/derivatives are examined, and the possible proposals for future directions to enhance the energy conversion and storage performance are reviewed.

show abstract

Section: Synthesis Of Iron and Titanium-based 2dmentioning

confidence: 99%

Recent Advances and New Challenges: Two-Dimensional Metal–Organic Framework and Their Composites/Derivatives for Electrochemical Energy Conversion and Storage

Nivetha

Sharma

Jana

et al. 2023

International Journal of Energy Research

View full text Add to dashboard Cite

show abstract

“…Thus, MOFs have gained attention in solar photocatalysis since MOFs can be activated by irradiation transferring electrons from the organic linker to the unoccupied d-orbitals of the metal cluster by a mechanism known as ligand-to-metal charge transfer (LMCT) [19,20]. Among the most used MOFs, Fe-based (as MIL-53, -88 and -101), Ti-(MIL-125), Zr-(UiO-66), and Zn-MOFs (ZIF-8) are the most popular, and all their derivatives have been described to enhance the solar light harvesting [21][22][23][24].…”

Section: Introductionmentioning

confidence: 99%

Novel isoreticular UiO-66-NH2 frameworks by N-cycloalkyl functionalization of the 2-aminoterephtalate linker with enhanced solar photocatalytic degradation of acetaminophen

Gómez-Avilés

Solís

García-Frutos

et al. 2023

Chemical Engineering Journal

View full text Add to dashboard Cite

“…MOF metal centers act as templates, connecting to organic linkers via coordinative metal-ligand interactions and electrostatic attraction. MOFs esthetical chemistry is determined by the interaction of a specific metal secondary building unit with organic ligands [2]. The organic linker may have the same topology but a different metric, creating an isoreticular set of structures that share the same basic net.…”

Section: Introduction 11 General Introductionmentioning

confidence: 99%

Historical Developments in Synthesis Approaches and Photocatalytic Perspectives of Metal-Organic Frameworks

Muslim¹,

Ahmad²

2023

Photocatalysts - New Perspectives

View full text Add to dashboard Cite

Metal–organic frameworks (MOFs) have witnessed fast-growing development in inorganic chemistry as well as material chemistry due to their attractive tunable property, structural specificity, high surface area, and porosity of 3D structures. The conventional semiconductor nature of MOFs is dependent on the photoactive organic ligands and their optimization with incorporated active metal center ion, which have enjoyed these properties in the photocatalytic mechanism via efficient photogenerated charge carriers under the illumination of sunlight (UV-Visible) and other different types of lights. To improve photocatalytic efficiency, a wide range of MOFs could be easily designed to cover and harvest UV irradiation from the sunlight. A wide variety of MOFs have been designed and synthesized as photocatalysts for photocatalytic degradation of organic pollutants, photocatalytic specific redox in organic synthesis, and function in photoelectrodes. In addition, the mechanisms and current challenges for MOFs in photocatalytic degradation of organic pollutants will be thoroughly discussed. This chapter discusses recent research advances in the use of MOFs as emerging photocatalysts.

show abstract

Iron-based metal-organic framework: Synthesis, structure and current technologies for water reclamation with deep insight into framework integrity

Cited by 114 publications

References 268 publications

Recent Advances and New Challenges: Two-Dimensional Metal–Organic Framework and Their Composites/Derivatives for Electrochemical Energy Conversion and Storage

Recent Advances and New Challenges: Two-Dimensional Metal–Organic Framework and Their Composites/Derivatives for Electrochemical Energy Conversion and Storage

Novel isoreticular UiO-66-NH2 frameworks by N-cycloalkyl functionalization of the 2-aminoterephtalate linker with enhanced solar photocatalytic degradation of acetaminophen

Historical Developments in Synthesis Approaches and Photocatalytic Perspectives of Metal-Organic Frameworks

Contact Info

Product

Resources

About