A Thomson parabola ion spectrometer, implemented on the Laboratory for Laser Energetics Multi-Terawatt laser facility, has been used to study heavy-ion acceleration from ultra-intense laser-plasma interactions. These studies were conducted using 20 lm-thick flat foil targets with on-target intensities of 4À5 Â 10 19 W-cm À2. Several charge states of energetic heavy ions were accelerated from the rear of Al and Cu foils in the presence of hydrocarbon contaminants. In contrast to previous work, we show that the mean and maximum energies of each heavy-ion species scale linearly with only the charge of the ion, and not the charge-to-mass ratio, implying that the space-charge is not readily depleted as ions expand. It has been shown previously and observed here that the maximum heavy-ion energies are lower than that of protons, though a fundamental explanation for this discrepancy has not been provided. We show how a two-temperature electron distribution, observed in these experiments, explains these observations.