2007
DOI: 10.1002/chin.200739118
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Simon J. Meek,
Emmanuel H. Demont,
Joseph P. A. Harrity

Abstract: Investigation of the Scope of an Enantioselective Co-Mediated O→C Rearrangement Reaction. -Enantioenriched pyranyl enol ethers undergo Lewis acid promoted rearrangement to give substituted cyclohexanones with good enantiocontrol. In contrast, dihydropyrans rearrange to give cyclobutane derivatives with complete racemization. -(MEEK, S. J.; DEMONT, E. H.; HARRITY*, J. P. A.; Tetrahedron Lett. 48 (2007) 24, 4165-4168; Dep. Chem., Univ. Sheffield, Sheffield S3 7HF, UK; Eng.) -Mais 39-118

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