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Cited by 27 publications
(6 citation statements)
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“…Nikolajenko et al . [ 194 ] reported a similar particle size effect in benzene hydrogenation under similar reaction conditions over Ni/MgO catalysts, where the activity dropped largely when Ni particel size was below ~7 nm (Curve 3 in Figure 23).…”
Section: Particle Size Effect In Metal Catalysismentioning
confidence: 75%
See 1 more Smart Citation
“…Nikolajenko et al . [ 194 ] reported a similar particle size effect in benzene hydrogenation under similar reaction conditions over Ni/MgO catalysts, where the activity dropped largely when Ni particel size was below ~7 nm (Curve 3 in Figure 23).…”
Section: Particle Size Effect In Metal Catalysismentioning
confidence: 75%
“…[ 193 ] and Nikolajenko et al . [ 194 ] Through kinetic analysis, they found that the activation energy was almost the same on those Ni catalysts with different sizes, showing that the reaction mechanism dose not change with particle size, thus excluding the possible electronic effect in the activity change. They proposed that the active sites involved a certain number of adjacent metal atoms (4 or more atoms), which is favorable for benzene adsorption through the interaction of delocallized π‐ring with flat metal surfaces.…”
Section: Particle Size Effect In Metal Catalysismentioning
confidence: 99%
“…Nickel catalysts have been used for several years for many industrial processes, such as hydrogenation, dehydrogenation, hydrogenolysis, reforming, and gas shift conversion due to its availability, high activity, and selectivity (Nikolajenko et al, 1963;Areshidze and Chivadze, 1976;Vannice and Garten, 1979;Bruch and Flambard, 1981;Corma et al, 1988;Burke and Ko, 1989). It could be a cheap substitute for plate-forming catalyst either in the form of Raney nickel or supported on different materials.…”
Section: Introductionmentioning
confidence: 99%
“…Nickel catalysts have been used for several years for many industrial processes, such as hydrogenation, dehydrogenation, hydrogenolysis, reforming and gas shift conversion due to its availability, high activity and selectivity [1][2][3][4][5][6], It could be a cheap substitute for plate forming catalyst either in the form of Raney nickel, or supported on different materials.…”
Section: -Introductionmentioning
confidence: 99%