2007
DOI: 10.1002/chin.200741022
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Marcella Pani,
Franco Merlo,
Maria L. Fornasini

Abstract: Copper I 7400Intermetallic Phases in the Ca-Cu-Sn System. -Twelve ternary alloys of the title system are synthesized by melting mixtures of the elements (sealed Ta crucibles, induction furnace) and subsequent annealing at 600-700°C. Four ordered compounds are detected and their structures are determined by single crystal XRD. CaCuSn crystallizes with YbAuSn type structure in the orthorhombic space group Imm2 with Z = 12, Ca3Cu8Sn4 is isotypic with Nd3Co8Sn4 (hexagonal, space group P63mc, Z = 2), CaCu 2 Sn 2 r…

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