Recent efficiency
records of organic photovoltaics (OPV) highlight stability as a limiting
weakness. Incorporation of stabilizers is a desirable approach for
inhibiting degradationit is inexpensive and readily up-scalable.
However, to date, such additives have had limited success. We show
that β-carotene (BC), an inexpensive and green, naturally occurring
antioxidant, dramatically improves OPV stability. When compared to
nonstabilized reference devices, the accumulated power generation
of PTB7:[70]PCBM devices in the presence of BC increases by an
impressive factor of 6, due to stabilization of both the burn-in and
the lifetime, and by a factor of 21 for P3HT:[60]PCBM devices, owing
to a longer lifetime. Using electron spin resonance and time-resolved
near-IR emission spectroscopies, we probed radical and singlet oxygen
concentrations. We demonstrate that singlet oxygen sensitized by [70]PCBM
causes the “burn-in” of PTB7:[70]PCBM devices and that
BC effectively mitigates it. Our results provide an effective solution
to the problem that currently limits widespread use of OPV.