Liquid crystalline physical gels (LCPGs) have attracted
increasing
interest because of their mechanical properties and stimulus–response
behaviors. However, due to their gelator properties such as thermal
stability, gelation capability, and compatibility in liquid crystals,
development of LCPGs with high performances still remains a huge challenging
task. Herein, four novel gelators ((l)-PH, (d)-PH,
(l)-P2H, and (d)-P2H) based on 1,4-benzenedicarboxamide
phenylalanine derivatives containing one or two ethylene glycol groups
have been designed and synthesized. It is found that the ethylene
glycol group plays a significant role in improving the compatibility
between the gelator and the liquid crystal. All of the prepared compounds
can form stable LCPGs in P0616A. In particular, the storage modulus
of LCPG with 9.0 wt % of (l)-PH with one ethylene glycol
unit is higher than 106 Pa, which is similar to SmC gels
and advantageous over previously reported nematic LCPGs. Furthermore,
the prepared gels display a strong Cotton effect with hand-preferred
twisted fiber networks and the self-assembled aggregates of (l)-PH can induce P0616A to form a cholesteric fingerprint structure.
Thus, these low molecular weight gelators provide a strategy to construct
high-performance cholesteric LCPGs for the realization of LC device
applications.