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“…of a chiral template and two oppositely charged porphyrins [2,5,7,9−12]. It was proved that metallation of the cationic or anionic porphyrin significantly influences the dimensions and spectral properties of the resulting aggregate [12]. The most promising results were obtained using a polyglutamic matrix, cationic porphyrin CuT4, and anionic porphyrin TPPS [5].…”
Section: Cationic Meso-tetrakis(α-trimethylammonio-ptolyl)porphyrin (mentioning
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rupbmjkragerfmgwileyiopcupepmcmbcthiemesagefrontiersapsiucrarxivemeralduhksmucshluniversity-of-gavle
“…of a chiral template and two oppositely charged porphyrins [2,5,7,9−12]. It was proved that metallation of the cationic or anionic porphyrin significantly influences the dimensions and spectral properties of the resulting aggregate [12]. The most promising results were obtained using a polyglutamic matrix, cationic porphyrin CuT4, and anionic porphyrin TPPS [5].…”
Section: Cationic Meso-tetrakis(α-trimethylammonio-ptolyl)porphyrin (mentioning
“…Fig. 2 shows influence of a solvent on Soret and Q bands, an assignment of the bands was in the reports [10]. While the spectra in DMSO, DMF and ethanol have similar shapes (four components of Q band, visible shoulder on UV side of Soret band), the spectrum in methanol is definitely different.…”
Section: Resultsmentioning
“…This makes them excellent building blocks, which can create supramolecular architectures with very good spectroscopic properties [2,10]. They can potentially be used as sensors, opto-electronic devices, antenna systems, etc.…”
Section: Introductionmentioning
“…1). 22 We chose to use only the free-base and copper derivatives ( Fig. 1) because penta-or hexa-coordinated porphyrins or planar metalloderivatives bearing a positive charge in the inner core (as the gold(III) derivatives) lead to the formation of supramolecular species for which the chiral memory phenomenon does not occur.…”
Section: Methodsmentioning