Hydrophobic modification of wood via surface-initiated ARGET ATRP of MMA

Fu, Yanchun; Li, Gang; Yu, Haipeng; Liu, Yixing

doi:10.1016/j.apsusc.2011.10.087

Cited by 71 publications

(52 citation statements)

References 26 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…SARA ATRP works well in organic solutions and ensures good control over polymerization. Cellulose functional materials have been successfully synthesized by using ARGET and SARA ATRP [83,96,105,111,115,117,162].…”

Section: Atrp Of Cellulosementioning

confidence: 99%

Graft modification of cellulose: Methods, properties and applications

Kang

Liu

Huang

2015

Polymer

192

View full text Add to dashboard Cite

Section: Atrp Of Cellulosementioning

confidence: 99%

Graft modification of cellulose: Methods, properties and applications

Kang

Liu

Huang

2015

Polymer

192

View full text Add to dashboard Cite

“…Numerous monomers have been grafted onto natural materials via ATRP or ARGET-ATRP, such as methyl methacrylate (Castelvetro et al 2006 ;Xu et al 2009 ;Fu et al 2012 ), ethyl acrylate (Meng et al 2009 ), styrene (Meng et al 2009 ;Morandi et al 2009 ), methyl acrylate (Carlmark and Malmstr ö m 2002 ), 2-(dimethylamino)ethyl methacrylate (DMAEMA) (Zhang et al 1998 ;Lee et al 2004 ;Wang et al 2011 ), glycidyl methacrylate (Lindqvist et al 2008 ), N -isopropylacrylamide (Zampano et al 2009 ), and 4-vinylpyridine (Hansson et al 2009 ).…”

Section: Introductionmentioning

confidence: 99%

Antimicrobial surfaces of quaternized poly[(2-dimethyl amino)ethyl methacrylate] grafted on wood via ARGET ATRP

Yu¹,

et al. 2012

Holzforschung

Self Cite

View full text Add to dashboard Cite

In special applications, such as hospitals and rehabilitation centers, hygienic wood surface with antimicrobial performance is recommendable. In the present study, the antimicrobial property of wood was increased by grafting with 2-(dimethylamino)ethyl methacrylate (DMAEMA). The reaction proceeds via radical polymerization, and analysis via Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy, and thermogravimetric analysis confirmed the successful grafting of DMAEMA to wood. The tertiary amino groups of the immobilized P(DMAEMA) were then quaternized by an alkyl halide, and the quaternary ammonium groups at the surface in high concentration proved to be antibacterial. The test against Escherichia coli by means of the optical density method revealed that the bactericidal effect of the modified surface is higher than that of wood and the monomeric precursors of grafting.

show abstract

“…These drawbacks can be overcome by an improved ATRP technique, activators regenerated by electron transfer for ATRP (ARGET ATRP) process, which has been developed by Matyjaszewski's group more recently and greatly reduced sensitivity to oxygen by the introduction of an excess of reducing agent in the reaction [42,43]. Surface modification of solid cellulose and related materials, such as filter paper, cellulose membranes and wood, has been already investigated by several researchers [44][45][46][47], but information concerning grafted cotton fabric is rather scarce in the literature [48].…”

Section: Introductionmentioning

confidence: 99%

Polymer-grafted modification of cotton fabrics by SI-ARGET ATRP

Dong

Bao

et al. 2015

Fibers Polym

View full text Add to dashboard Cite

Cotton fabrics with sophisticated surface-specific properties were obtained by grafting poly(tert-butyl acrylate) (PtBA), poly(acrylic acid) (PAA), poly(oligo(ethylene oxide) monomethyl ether methacrylate) (POEOMA), poly(N,Ndimethylaminoethyl methacrylate) (PDMAEMA) and quaternized PDMAEMA (QPDMAEMA) bushes on cotton surfaces using surface-initiated activators regenerated by electron transfer atom transfer radical polymerization (SI-ARGET ATRP) of three rather different monomers in a water-ethanol solvent. Due to the different physical properties and chemical composition of grafted polymers, the properties of such obtained cotton fabrics can be tailored including mechanical properties from enhanced tensile strength to increased breaking elongation, hydrophilic/hydrophobic characteristics from superhydrophilic to hydrophobic, varied water absorption abilities, different dye adsorption capabilities and charge properties. This work presents a high potential surface modification route towards functional textiles which are expected to play an important role in the future applications.

show abstract

Hydrophobic modification of wood via surface-initiated ARGET ATRP of MMA

Cited by 71 publications

References 26 publications

Graft modification of cellulose: Methods, properties and applications

Graft modification of cellulose: Methods, properties and applications

Antimicrobial surfaces of quaternized poly[(2-dimethyl amino)ethyl methacrylate] grafted on wood via ARGET ATRP

Polymer-grafted modification of cotton fabrics by SI-ARGET ATRP

Contact Info

Product

Resources

About