1998
DOI: 10.1002/(sici)1099-1395(199808/09)11:8/9<584::aid-poc59>3.0.co;2-f
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Hydrolysis ofN-methyl-N-nitroso-p-toluenesulphonamide in micellar media
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Cited by 24 publications
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“…For a quantitative analysis of the microemulsion effect on the solvolysis, it is necessary to propose a model which allows the determination of the concentration of reactants in the different regions of the microemulsion as well as the corresponding rate constants. The pseudophase model, , originally developed for aqueous micellar systems, has been extended to other colloidal aggregates such as vesicles and microemulsions with satisfactory results. − This model considers the microemulsion divided in three regions (water, oil, and interface) between which the reactants are distributed. − In the most general scenario, the benzoyl halides can be distributed in the three pseudophases, and consequently the reaction can take place at both the aqueous pseudophase and the interface of the microemulsion (see Scheme ).…”
Section: Resultsmentioning
confidence: 99%
“…For a quantitative analysis of the microemulsion effect on the solvolysis, it is necessary to propose a model which allows the determination of the concentration of reactants in the different regions of the microemulsion as well as the corresponding rate constants. The pseudophase model, , originally developed for aqueous micellar systems, has been extended to other colloidal aggregates such as vesicles and microemulsions with satisfactory results. − This model considers the microemulsion divided in three regions (water, oil, and interface) between which the reactants are distributed. − In the most general scenario, the benzoyl halides can be distributed in the three pseudophases, and consequently the reaction can take place at both the aqueous pseudophase and the interface of the microemulsion (see Scheme ).…”
Section: Resultsmentioning
confidence: 99%
