Hydrogenation and Dehydrogenation

Antiproliferative and Antifungal Activity of Penicillic Acid in Comparison with Its Different Derivatives

“…This mixture was degassed using vacuum pump fitted with a H 2 gas source. [11][12][13] This reaction mixture was stirred with small magnetic stirrer for 12 h. The reaction product was passed over silica gel in a small glass column to filter out the unwanted materials. The reduced product was present in supernatant solution.…”

Antiproliferative and Antifungal Activity of Penicillic Acid in Comparison with Its Different Derivatives

“…This mixture was degassed using vacuum pump fitted with a H 2 gas source. [11][12][13] This reaction mixture was stirred with small magnetic stirrer for 12 h. The reaction product was passed over silica gel in a small glass column to filter out the unwanted materials. The reduced product was present in supernatant solution.…”

Discovery of a New Solvent Co-Catalyzed Mechanism in Heterogeneous Catalysis: A First-Principles Study with Molecular Dynamics on Acetaldehyde Hydrogenation on Birnessite

“…Hydrogenation reactions in heterogeneous catalysis are among the most important reactions. In particular, the hydrogenation of aldehydes is vital in a plethora of industrial applications, which include the food, petrochemical, and fragrance industries. − However, traditional mechanisms in heterogeneous catalysis become pinched in facing a wide range of catalysts and a variety of reaction environments . In this letter, we present a novel solvent-cocatalyzed hydrogenation mechanism that bypasses the overly strong adsorption of key reactants, using acetaldehyde hydrogenation on birnessite as an example.…”

Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis Pairs

“…Catalytic hydrogenation of unsaturated substrates is one of the most fundamental transformations in chemistry. It is pertinent to biological systems and employed in a plethora of industrial chemical processes . Our ability to effect such reductions has its genesis in the seminal discovery by Sabatier in the early 1900s .…”

Antiproliferative and Antifungal Activity of Penicillic Acid in Comparison with Its Different Derivatives

“…This mixture was degassed using vacuum pump fitted with a H 2 gas source. [11][12][13] This reaction mixture was stirred with small magnetic stirrer for 12 h. The reaction product was passed over silica gel in a small glass column to filter out the unwanted materials. The reduced product was present in supernatant solution.…”

Discovery of a New Solvent Co-Catalyzed Mechanism in Heterogeneous Catalysis: A First-Principles Study with Molecular Dynamics on Acetaldehyde Hydrogenation on Birnessite

“…Hydrogenation reactions in heterogeneous catalysis are among the most important reactions. In particular, the hydrogenation of aldehydes is vital in a plethora of industrial applications, which include the food, petrochemical, and fragrance industries. − However, traditional mechanisms in heterogeneous catalysis become pinched in facing a wide range of catalysts and a variety of reaction environments . In this letter, we present a novel solvent-cocatalyzed hydrogenation mechanism that bypasses the overly strong adsorption of key reactants, using acetaldehyde hydrogenation on birnessite as an example.…”

Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis Pairs

“…Catalytic hydrogenation of unsaturated substrates is one of the most fundamental transformations in chemistry. It is pertinent to biological systems and employed in a plethora of industrial chemical processes . Our ability to effect such reductions has its genesis in the seminal discovery by Sabatier in the early 1900s .…”

Antiproliferative and Antifungal Activity of Penicillic Acid in Comparison with Its Different Derivatives

“…This mixture was degassed using vacuum pump fitted with a H 2 gas source. [11][12][13] This reaction mixture was stirred with small magnetic stirrer for 12 h. The reaction product was passed over silica gel in a small glass column to filter out the unwanted materials. The reduced product was present in supernatant solution.…”

Discovery of a New Solvent Co-Catalyzed Mechanism in Heterogeneous Catalysis: A First-Principles Study with Molecular Dynamics on Acetaldehyde Hydrogenation on Birnessite

“…Hydrogenation reactions in heterogeneous catalysis are among the most important reactions. In particular, the hydrogenation of aldehydes is vital in a plethora of industrial applications, which include the food, petrochemical, and fragrance industries. − However, traditional mechanisms in heterogeneous catalysis become pinched in facing a wide range of catalysts and a variety of reaction environments . In this letter, we present a novel solvent-cocatalyzed hydrogenation mechanism that bypasses the overly strong adsorption of key reactants, using acetaldehyde hydrogenation on birnessite as an example.…”

Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis Pairs

“…Catalytic hydrogenation of unsaturated substrates is one of the most fundamental transformations in chemistry. It is pertinent to biological systems and employed in a plethora of industrial chemical processes . Our ability to effect such reductions has its genesis in the seminal discovery by Sabatier in the early 1900s .…”